Hydrophobic Magnetic Carrier Particles for Ultraflotation Separation

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Solution Overview

Problem

Existing separation processes for hydrophobic or hydrophobized materials from mixtures are inefficient, leading to low yield and potential contamination from toxic compounds like chromium, which increases processing costs and risks.

Innovation Solution

A process involving contacting the dispersion with hydrophobic or hydrophobized magnetic particles, followed by air flotation to separate magnetic agglomerates, and then disaggregating and separating the magnetic particles using a magnetic field.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If magnetic particles are used to separate hydrophobic materials from mixtures, then separation efficiency is improved, but bond strength between magnetic particles and target material is insufficient leading to low yield

Engineering Contradiction:
Improveseparation efficiencyVSAvoidbond strength
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

A hydrophobizing agent is introduced as an intermediary substance that bridges the magnetic particles and the hydrophobic target material. The agent first adsorbs onto the magnetic particle surface, then binds to the hydrophobic material through hydrophobic interactions, creating a strong indirect bond that overcomes the insufficient direct bonding between magnetic particles and target material

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The system forms a composite structure consisting of magnetic particles coated with hydrophobizing agent that are bound to hydrophobic target material. This composite agglomerate combines the magnetic properties of the particles with the hydrophobic characteristics of the target material, enabling effective separation while maintaining strong bonds

Inventive Principle:
Principle #40Composite materials

2Device complexity

If conventional separation processes are used, then processing is simpler, but contamination from toxic compounds like chromium increases

Engineering Contradiction:
Improveprocess complexityVSAvoidcontamination risk
Core Design Contradiction:
Device complexityVSObject-affected harmful factors

Solution Approach 1:

The hydrophobizing agent is selectively applied only to the magnetic particles rather than being present throughout the entire mixture. This targeted application allows the agent to mediate binding between magnetic particles and target material without causing widespread contamination of toxic compounds like chromium in the bulk mixture

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The hydrophobizing agent acts as a controlled intermediary that enables separation through specific hydrophobic interactions, replacing conventional methods that require harsh chemicals or complex treatment processes. This reduces exposure to toxic compounds while achieving effective separation

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enhances separation efficiency, increases yield, and reduces the risk of contamination by effectively isolating valuable materials while minimizing the use of apparatuses, thus improving the overall recovery process.

Implementation Method 1

contacting the dispersion with hydrophobic or hydrophobized magnetic particles to provide a dispersion I comprising at least one magnetic agglomerate comprising the at least one hydrophobic or hydrophobized material and the at least one hydrophobic or hydrophobized magnetic particle

Methodology Applied
Scientific EffectHydrophobic interaction: Hydrophobe

Implementation Method 2

separating the at least one magnetic agglomerate from the dispersion I of step (A) by subjecting the dispersion I to air flotation

Methodology Applied
Scientific EffectAir flotation: Froth Floatation

Implementation Method 3

separating the at least one hydrophobic or hydrophobized material from the magnetic particles by applying a magnetic field

Methodology Applied
Scientific EffectMagnetic field: Magnetic Field

Data Source

PatentEP3389872B1Ultraflotation with magnetically responsive carrier particles
Publication Date: 2025.10.22 BASF SE
  • EP3389872B1 patent drawing
  • EP3389872B1 patent drawing
  • EP3389872B1 patent drawing

AI summary

The present invention relates to a process for the separation of at least one hydrophobic or hydrophobized material from a dispersion comprising said at least one hydrophobic or hydrophobized material and at least one second material. The process according to the present invention comprises the steps (A) to (D) which are described herein.