Magnetic Color-Changeable Microcapsules for Stable Photonic Crystal Arrangement

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Solution Overview

Problem

Conventional printing methods using magnetic-color-changeable microcapsules face challenges in achieving stable color retention after curing, as the arrangement of photonic crystals can be disturbed by external magnetic fields, and the curable solvent hinders the movement of nanoparticles, making it difficult to achieve desired color arrangements.

Innovation Solution

A composition comprising magnetic-color-changeable microcapsules with a curable solvent having a specific weight-average molecular weight and viscosity, along with a magnetic field generation unit and energy regulation unit, is used to control the arrangement of electrically charged nanoparticles within the microcapsules, ensuring stable color retention even after exposure to strong magnetic fields.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If a curable solvent is used to disperse photonic crystals in magnetic-color-changeable microcapsules, then the composition can be jetted and printed onto a printing medium, but the curable solvent inhibits the movement of photonic crystals making it difficult to achieve desired color arrangements

Engineering Contradiction:
ImproveprintabilityVSAvoidphotonic crystal arrangement
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent applies a magnetic field before the curable solvent fully cures to arrange the photonic crystals in the desired configuration. This preliminary action occurs while the solvent is still in a mobile state, allowing crystal movement, but before curing locks the arrangement in place, thus resolving the contradiction between printability and arrangement stability.

Inventive Principle:
Principle #10Preliminary action

2Adaptability or versatility

If photonic crystals are arranged by applying a magnetic field, then color-changing effects are achieved, but the arrangement may be disturbed by external magnetic fields even after curing

Engineering Contradiction:
Improvecolor-changing effectVSAvoidcolor stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent utilizes the phase transition of the curable solvent from liquid to solid state through curing. In the liquid state, photonic crystals can move and rearrange in response to magnetic fields for color changing. After curing transitions to solid state, the crystals are locked in position, providing color stability while maintaining the ability to change color when needed through controlled magnetic field application.

Inventive Principle:
Principle #36Phase transitions

3Device complexity

If multiple colors are printed using a single cartridge with magnetic-color-changeable microcapsules, then device complexity is reduced, but manufacturing precision of color arrangement becomes more difficult

Engineering Contradiction:
Improvecartridge systemVSAvoidcolor arrangement
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent changes the magnetic field parameters (strength, direction, timing) to control photonic crystal arrangement for different colors. By varying these parameters during the printing process, a single cartridge can produce multiple colors with precise arrangements, reducing device complexity while maintaining manufacturing precision through parameter control rather than physical structure.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition exhibits stable color changes and retention, suitable for fast curing and repeated exposure to magnetic fields, enhancing the performance of printing devices like handheld writing instruments by maintaining color stability and sharpness.

Implementation Method 1

a curable solvent having a specific weight-average molecular weight and viscosity

Methodology Applied
Scientific EffectFluidity:

Implementation Method 2

a magnetic field generation unit and energy regulation unit, is used to control the arrangement of electrically charged nanoparticles within the microcapsules

Methodology Applied
Scientific EffectMagnetic field: Magnetic Field

Implementation Method 3

based on the principle by which photonic crystals that constitute the magnetic-color-changeable microcapsules are arranged differently depending on the magnetic field strength to thereby vary the wavelength of reflected light

Methodology Applied
Scientific EffectPhotonic crystal: Photonic Crystal

Implementation Method 4

a curable solvent surrounding the photonic crystals is cured and, thus, the mobility of the arranged photonic crystals is reduced

Methodology Applied
Scientific EffectCuring: Photopolymerisation

Data Source

PatentEP3774348B1Composition comprising magnetic color changeable microcapsules and related cartidge, handheld writing device, printing method and printed medium
Publication Date: 2023.11.01 SOCIETE BIC SA
  • EP3774348B1 patent drawingFigure 1(a)~1(b)
  • EP3774348B1 patent drawingFigure 2(a)~2(b)
  • EP3774348B1 patent drawingFigure 3~4d

AI summary

This disclosure relates to a printing device for printing or dispensing a curable printing composition which is capable of changing color in response to the application of a magnetic field in the non-cured state. The printing device may be a handheld device such as a portable pen. The present disclosure further relates to curable compositions, cartridges and methods which may be used in combination with the aforementioned printing devices or in other applications.