Magnetic Core Material for Electrophotographic Developer

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Solution Overview

Problem

Existing electrophotographic developers face challenges in maintaining stable image characteristics, particularly in high-speed printing, due to low rising-up speed of charge amount and durability issues related to carrier particle characteristics, such as compression breaking strength and variation, which lead to toner scattering and image defects.

Innovation Solution

A magnetic core material with controlled sulfur component content (50-700 ppm) and BET specific surface area (0.06-0.25 m^2/g) is developed, enhancing charge imparting ability and compression breaking strength while reducing variation, and a resin-coated carrier is used to improve carrier performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional carrier particles are used in two-component developers, then the developer can function for basic electrophotographic development, but the rising-up speed of charge amount is slow and durability is insufficient for high-speed printing

Engineering Contradiction:
Improverising-up speed of charge amountVSAvoiddurability of carrier particle
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The invention changes the chemical composition parameters of the carrier particle by incorporating specific amounts of sulfur (0.01-5 mass%) and chlorine (0.01-5 mass%) into the ferrite core material. This compositional modification fundamentally alters the charge generation mechanism, enabling rapid charge rising-up speed while maintaining structural durability for high-speed printing applications.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite carrier particle structure consisting of a ferrite core material with controlled sulfur and chlorine content, optionally coated with resin. This composite approach combines the magnetic properties of ferrite with the charge-enhancing effects of sulfur and chlorine, achieving both fast charging and durability required for high-speed printing.

Inventive Principle:
Principle #40Composite materials

2Reliability

If trace elements are added to ferrite composition to improve carrier characteristics, then charge amount and durability are enhanced, but image quality deteriorates due to toner scattering and fogging

Engineering Contradiction:
Improvedurability of carrier particleVSAvoidimage quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The invention precisely controls the concentration parameters of sulfur (0.01-5 mass%) and chlorine (0.01-5 mass%) within narrow ranges. This precise parameter control ensures sufficient trace elements are present to enhance charge amount and durability, while preventing excessive accumulation that would cause toner scattering and fogging, thus maintaining high image quality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention establishes feedback control by defining specific concentration ranges for sulfur and chlorine based on their dual effects. The lower limits ensure adequate charge enhancement and durability, while the upper limits prevent image quality degradation, creating a self-regulating composition specification that balances durability and image quality.

Inventive Principle:
Principle #23Feedback

3Strength

If carrier particle compression breaking strength is increased to improve durability, then durability is enhanced, but variation in strength increases leading to unstable image characteristics

Engineering Contradiction:
Improvecompression breaking strength of carrier particleVSAvoiduniformity of carrier particle characteristics
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The invention modifies the core material composition by incorporating sulfur and chlorine, which fundamentally changes the material properties to achieve both high compression breaking strength (200-500 mN) and low strength variation (coefficient of variation ≤30%). This compositional change ensures uniform charge characteristics across all carrier particles while maintaining high durability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The magnetic core material achieves rapid charge rising-up, high compression breaking strength, and reduced variation, resulting in stable and high-quality images with improved durability and reduced defects in electrophotographic developers.

Implementation Method 1

a carrier particle is a carrier substance which is agitated with a toner particle in a development box filled with the developer to impart a desired charge to the toner particle

Methodology Applied
Scientific EffectCharge imparting: Triboelectric Effect

Implementation Method 2

a magnet roll is now in the mainstream... The carrier particle remaining on a development roll to hold a magnet

Methodology Applied
Scientific EffectMagnetism: Magnetism

Data Source

PatentEP3567430B1Magnetic core material for electrographic developer, carrier for electrographic developer, and developer
Publication Date: 2024.03.13 POWDERTECH CO LTD
  • EP3567430B1 patent drawingFigure 1
  • EP3567430B1 patent drawing
  • EP3567430B1 patent drawing

AI summary

Provided are a magnetic core material for electrophotographic developer and a carrier for electrophotographic developer, which are excellent in charge characteristics and strength and with which a satisfactory image free from defects can be obtained, and a developer containing the carrier. A magnetic core material for electrophotographic developer, having a sulfur component content of from 50 to 700 ppm in terms of a sulfate ion and a BET specific surface area of from 0.06 to 0.25 m2/g.