Magnetic Goniochromic Articles Liquid Coating Process

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Solution Overview

Problem

Current manufacturing methods for goniochromatic articles with high flop and metallic appearance are expensive, require complex equipment, and limit the use of materials to those that can be vaporized under low pressure, leading to poor interlayer adhesion and productivity issues due to vacuum processing.

Innovation Solution

The development of articles comprising a magnetic-containing layer with external reflector and selective light modulator layers, using a liquid coating process that includes curing agents and oxygen inhibition mitigation compositions to enhance optical properties and reduce equipment complexity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If vapor deposition processes are used to manufacture goniochromatic articles, then optical properties can be achieved, but equipment complexity and cost increase significantly

Engineering Contradiction:
Improveoptical propertiesVSAvoidequipment complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces the mechanical vapor deposition system with a chemical solution-based coating system. Instead of using vacuum chambers and vapor deposition equipment to deposit metal layers, the invention uses liquid coating processes with curable compositions that can be applied via dip-coating, spray-coating, or other liquid application methods, eliminating the need for complex vacuum equipment while achieving similar optical interference effects

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the physical state of the coating material from vapor phase (in vapor deposition) to liquid phase (in the curable composition). This parameter change allows the use of simpler liquid application equipment instead of complex vacuum deposition equipment, while the curable nature of the composition ensures proper adhesion and structural integrity of the layered optical structure

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If vapor deposition processes are used to manufacture goniochromatic articles, then optical properties can be achieved, but productivity decreases due to vacuum processing requirements

Engineering Contradiction:
Improveoptical propertiesVSAvoidproductivity
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent replaces the vacuum-based vapor deposition process with a liquid coating process that can be performed at atmospheric pressure. This substitution eliminates the time-consuming vacuum pumping and venting cycles required in vapor deposition, allowing for continuous production and significantly improved productivity while maintaining the optical interference effects through proper layer thickness control in the curable composition

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent enables continuous coating operations by using liquid curable compositions that can be applied continuously via dip-coating or spray-coating methods. The curable nature of the composition allows for immediate or near-immediate processing without waiting for vacuum cycles to complete, enabling uninterrupted production and eliminating non-productive time associated with vacuum chamber maintenance and cycling

Inventive Principle:
Principle #20Continuity of useful action

3Manufacturing precision

If vapor deposition processes are used to manufacture goniochromatic articles, then optical properties can be achieved, but interlayer adhesion deteriorates

Engineering Contradiction:
Improveoptical propertiesVSAvoidinterlayer adhesion
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent changes the deposition method from physical vapor deposition to chemical curing of liquid compositions. The curable composition contains reactive monomers or oligomers that form covalent bonds with adjacent layers, providing strong interlayer adhesion. This chemical bonding mechanism is superior to the physical adhesion achieved in vapor deposition, resulting in enhanced interlayer strength while maintaining the optical interference effects through controlled layer thickness

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If vapor deposition processes are used to manufacture goniochromatic articles, then optical properties can be achieved, but material selection is limited to materials that can be vaporized under low pressure

Engineering Contradiction:
Improveoptical propertiesVSAvoidmaterial variety
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The patent changes the material delivery state from vapor phase to liquid phase, enabling the use of a broad range of materials that can be formulated into curable compositions. This includes organic materials, polymers, pigments, and functional additives that cannot be vaporized under low pressure but can be dissolved or dispersed in liquid carriers and then cured to form the required optical layers, significantly expanding material selection flexibility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite curable compositions that combine multiple materials within a single coating layer. These compositions can include polymer matrices with embedded pigments, fillers, and functional additives, allowing for tailored optical properties and enhanced performance. The composite nature of these materials enables the achievement of optical interference effects while incorporating materials that would be incompatible with vapor deposition processes

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution enables the production of goniochromatic articles with improved optical interference effects, increased material variety, and reduced production costs by using a liquid coating process that stabilizes the selective light modulator layers, enhancing productivity and interlayer adhesion.

Implementation Method 1

Articles that can (i) include a strong color, (ii) be goniochromatic, and (iii) have a high flop, i.e., a specular and metallic appearance that varies in lightness, hue, or chromaticity as the viewing angle varies

Methodology Applied
Scientific EffectOptical interference: Interference

Implementation Method 2

a first reflector layer external to the first surface of the magnetic containing layer; a second reflector layer external to the second surface of the magnetic containing layer

Methodology Applied
Scientific EffectLight reflection: Reflection

Data Source

PatentEP3584288B1Magnetic articles
Publication Date: 2021.08.18 VIAVI SOLUTIONS INC(US)
  • EP3584288B1 patent drawingFigure 1~3

AI summary

An article including a magnetic-containing layer having a first surface and a second surface opposite the first; a first reflector layer external to the first surface of the magnetic-containing layer; a second reflector layer external to the second surface of the magnetic-containing layer; a first selective light modulator layer external to the first reflector layer; a second selective light modulator layer external to the second reflector layer; a first absorber layer external to the first selective light modulator layer; and a second absorber layer external to the second selective light modulator layer; wherein at least one of the first and second selective light modulator layers comprises at least one of a curing agent, and at least one coating aid is disclosed. Methods of making the disclosed article are also disclosed.