Magnetic Memory Device Boron Concentration Control

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Solution Overview

Problem

High-temperature processes in magnetic memory device fabrication cause boron atoms in the free layer to spread into adjacent layers, deteriorating the device's characteristics by changing the amorphous magnetic material to a crystalline state and allowing excess oxygen to flow into the free layer, leading to reduced dispersion and reliability.

Innovation Solution

The magnetic memory device incorporates a free layer pattern, an oxide layer pattern, and a capping layer pattern with boron concentrations that are similar or equal to each other, minimizing the spread of boron atoms and maintaining the amorphous state, thereby enhancing dispersion and product reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If high-temperature processes are used in magnetic memory device fabrication, then manufacturing efficiency is improved, but boron atoms spread into adjacent layers causing crystalline phase transformation and excess oxygen flow, deteriorating device characteristics

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoidboron concentration uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

An oxygen barrier layer is introduced between the free layer containing boron and adjacent layers. This intermediary layer prevents oxygen diffusion from adjacent layers into the free layer during high-temperature processing, thereby preventing crystalline phase transformation while allowing the high-temperature process to maintain manufacturing efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent controls the boron concentration in the free layer to be within a specific range (5-20 at%) and maintains this concentration uniformity across the free layer thickness. By optimizing the boron concentration parameter, the material remains in amorphous phase during high-temperature processing while preventing excessive oxygen absorption that would cause crystallization.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If boron concentration in the free layer is increased to improve magnetic properties, then magnetic performance is enhanced, but boron spread into adjacent layers increases causing crystalline phase transformation

Engineering Contradiction:
Improvemagnetic performance stabilityVSAvoidamorphous phase stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The oxygen barrier layer acts as a mediator that protects the boron-containing free layer from oxygen diffusion during high-temperature processing. This allows the free layer to maintain higher boron concentrations (5-20 at%) for improved magnetic performance while preventing the crystalline phase transformation that would occur without the barrier layer.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes the boron concentration parameter in the free layer to be within 5-20 at%, which is sufficient to achieve desired magnetic properties while remaining below the threshold concentration that would cause crystalline phase transformation during high-temperature processing.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If high-temperature annealing is applied to improve device characteristics, then electrical properties are enhanced, but excess oxygen flows into the free layer causing crystalline phase transformation

Engineering Contradiction:
Improveelectrical property stabilityVSAvoidamorphous phase stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The oxygen barrier layer is introduced as an intermediary between the free layer and adjacent oxygen-containing layers. This barrier prevents oxygen diffusion into the free layer during high-temperature annealing processes, thereby preventing crystalline phase transformation while allowing the annealing to improve electrical properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The oxygen barrier layer creates an inert environment around the free layer during high-temperature processing. This protective barrier effectively isolates the free layer from oxygen in the surrounding environment, preventing oxidation and crystalline phase transformation during annealing while maintaining the beneficial electrical property improvements.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach improves the dispersion and reliability of the magnetic memory device by maintaining uniform boron concentrations across layers, preventing boron atom spread and maintaining the amorphous state, which is critical for stable performance.

Implementation Method 1

a tunnel barrier layer pattern between the pinned layer pattern and the free layer pattern

Methodology Applied
Scientific EffectQuantum mechanical tunneling:

Implementation Method 2

a STT-MRAM which stores information using a spin transfer torque (STT) phenomenon is being researched. The STT-MRAM may store information by inducing magnetization reversal by directly applying a current to a magnetic tunnel junction element

Methodology Applied
Scientific EffectSpin transfer torque:

Data Source

PatentUS20240284802A1Magnetic memory device and method for fabricating the same
Publication Date: 2024.08.22 SAMSUNG ELECTRONICS CO LTD
  • US20240284802A1 patent drawing
  • US20240284802A1 patent drawing
  • US20240284802A1 patent drawing

AI summary

A magnetic memory device and a method for fabricating the same are provided. The magnetic memory device includes a pinned layer pattern, a free layer pattern including boron (B), a tunnel barrier layer pattern between the pinned layer pattern and the free layer pattern, an oxide layer pattern spaced apart from the tunnel barrier layer pattern with the free layer pattern therebetween, the oxide layer pattern including a metal borate, and a capping layer pattern spaced apart from the free layer pattern with the oxide layer pattern therebetween, the capping layer pattern including a metal boride, wherein a difference between a boron concentration of the free layer pattern and a boron concentration of the oxide layer pattern is 10 at % or less, and a difference between the boron concentration of the oxide layer pattern and a boron concentration of the capping layer pattern is 10 at % or less.