Magnetic Nanoparticle Fluid for High-Speed Inkjet Printing

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Solution Overview

Problem

Current magnetizable fluids for inkjet printing face challenges in balancing increased shelf life with high print resolution and speed, as larger particles provide longer shelf life but settle, leading to slower printing and lower resolution.

Innovation Solution

Development of nanoparticle fluids with densely packed multi-metal compounds formed through nanosintering, dispersed in a solvent, which allows for high-speed and high-resolution printing while maintaining long-term shelf life, featuring nanoparticles with metal oxides and additives for improved stability and performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If large magnetizable particles are used, then shelf life is improved, but print resolution and print speed deteriorate due to settling

Engineering Contradiction:
Improveshelf lifeVSAvoidprint resolution
Core Design Contradiction:
Duration of action of stationary objectVSManufacturing precision

Solution Approach 1:

The patent changes the particle size parameter from large particles to nanoparticles (1-100 nm diameter), which fundamentally alters the fluid's behavior. The nanoparticles remain suspended due to Brownian motion and surface forces dominating over gravity, preventing settling while maintaining magnetic properties for long shelf life and enabling high-resolution printing.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining multiple metal oxides (Fe3O4, γ-Fe2O3, MnO, CoO, NiO, CuO, ZnO, TiO2, SiO2, Al2O3) in nanoparticle form within a single fluid system. This composite approach provides both the magnetic properties needed for shelf life and the small size needed for high-resolution printing, resolving the contradiction between particle size requirements.

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If large magnetizable particles are used, then shelf life is improved, but printing speed deteriorates

Engineering Contradiction:
Improveshelf lifeVSAvoidprinting speed
Core Design Contradiction:
Duration of action of stationary objectVSProductivity

Solution Approach 1:

By changing the particle size parameter to the nanoscale (1-100 nm), the patent eliminates settling behavior that limits printing speed. The nanoparticles remain uniformly suspended due to dominant surface forces and Brownian motion, allowing rapid inkjet deposition at high speeds while maintaining long shelf life through prevented aggregation and settling.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If small magnetizable particles are used, then print resolution is improved, but shelf life deteriorates due to shorter charge retention

Engineering Contradiction:
Improveprint resolutionVSAvoidshelf life
Core Design Contradiction:
Manufacturing precisionVSDuration of action of stationary object

Solution Approach 1:

The patent employs composite materials by formulating nanoparticles containing multiple metal oxides including magnetic phases (Fe3O4, γ-Fe2O3) combined with other oxides (MnO, CoO, NiO, CuO, ZnO, TiO2, SiO2, Al2O3). This composite structure provides both the small size (1-100 nm) needed for high print resolution and enhanced charge retention properties for extended shelf life, resolving the contradiction between particle size and charge retention duration.

Inventive Principle:
Principle #40Composite materials

4Manufacturing precision

If nanoparticle size is reduced, then print resolution is improved, but fluid stability deteriorates

Engineering Contradiction:
Improveprint resolutionVSAvoidfluid stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent uses composite materials by combining multiple metal oxides in nanoparticle form, where the composite structure provides both small size (1-100 nm) for high resolution and inherent stability. The diverse oxide composition creates stable formulations that resist aggregation and settling, maintaining fluid stability while achieving high print resolution.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

By changing the particle size parameter to the nanoscale (1-100 nm) and controlling the composition parameters through multi-metal oxide integration, the patent achieves a regime where surface forces and Brownian motion dominate over gravitational settling. This parameter change stabilizes the nanoparticle suspension, preventing aggregation and settling while maintaining high print resolution capability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The nanoparticle fluids enable inkjet drop formation at high speeds and resolutions, extending shelf life beyond 12 months, with improved print density and optical density, and resistance to separation by magnetic or gravitational forces, enhancing the security features in documents and commercial products.

Implementation Method 1

nanoparticle fluids for use with ink jet printing on substrates for magnetic reading include a suspension of nanoparticles including densely packed composites of multi-metal compounds formed by nanosintering the multi-metal compounds

Methodology Applied
Scientific EffectNanosintering: Sintering

Implementation Method 2

the fluids include a shelf life of at least 12 months by resisting separation by a magnetic field or gravitational force

Methodology Applied
Scientific EffectMagnetic field interaction: Magnetic Field

Implementation Method 3

The nanoparticle fluid properties permit dispensing from an inkjet printer at a rate of at least 2.5 m/s and at a resolution of at least 600 dpi

Methodology Applied
Scientific EffectInkjet droplet formation: Jet

Data Source

PatentUS9390846B2Magnetic fluid suitable for high speed and high resolution dot-on-demand inkjet printing and method of making
Publication Date: 2016.07.12 VILLWOCK THOMAS
  • US9390846B2 patent drawing
  • US9390846B2 patent drawing
  • US9390846B2 patent drawing

AI summary

A magnetic fluid composition include a suspension of nano-particles including cross-crystallized multi-metal compounds dispersed in a solvent, the cross-crystallized multi-metal compounds including at least two or more metals having different valencies or oxidation states, the metals selected from the group consisting of a monovalent metal (Me+), a divalent metal (Me2+), a trivalent metal (Me3+), a quadrivalent metal (Me4+) and a rare earth metal. The magnetic fluid having a viscosity and surface tension that permits dispensing from an inkjet printer at a rate of at least 2.5 m/s, at a resolution of at least 600 dpi, supporting jetting pulse frequencies of at least 15 KHz per nozzle (enabling high speed inkjet printing applications of at least 0.6 m/sec per individual nozzle row per print head), and enabling uninterrupted, industrial level print output of magnetic ink character recognition (MICR) code lines suitable for high speed magnetic data scanning per established industry regulations (ANSI X9).