Magnetic Recording Medium Surface Composition for Head Durability

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Solution Overview

Problem

Magnetic recording media face challenges in maintaining excellent electromagnetic conversion characteristics and preventing head element chipping during the green tape test (GTT), where frequent changes in magnetic recording media lead to increased wear and tear on the head, causing spacing loss and reduced performance.

Innovation Solution

A magnetic recording medium comprising a non-magnetic support with a magnetic layer containing ferromagnetic hexagonal ferrite powder, a binding agent, and an oxide abrasive, along with fatty acid or fatty acid amide components, optimized to achieve a specific XRD intensity ratio, vertical squareness ratio, C—H derived C concentration, and FIB abrasive diameter, which enhances electromagnetic conversion characteristics and reduces head element chipping.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the thickness of the protective layer of the head is increased to prevent head element chipping, then head durability is improved, but the distance between the surface of the magnetic layer and the reproducing element increases, causing spacing loss and deteriorating electromagnetic conversion characteristics

Engineering Contradiction:
Improvehead durabilityVSAvoidspacing loss
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent changes the physical and chemical parameters of the magnetic layer surface by controlling the particle size distribution of ferromagnetic powder (bimodal distribution with 0.5-2.0 μm and 2.0-5.0 μm particles), the content of binding agents (polyester resin 5-20 parts by mass, polyamide resin 5-20 parts by mass), and the addition of wax (5-20 parts by mass). These parameter changes modify the surface properties to reduce friction and prevent head element chipping during GTT, achieving head durability without increasing protective layer thickness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite magnetic layer structure combining ferromagnetic powder particles of different sizes (bimodal distribution), multiple binding agents (polyester and polyamide resins), and wax. This composite formulation creates a surface with optimized mechanical properties that resist wear and prevent head element chipping while maintaining electromagnetic conversion characteristics

Inventive Principle:
Principle #40Composite materials

2Reliability

If a magnetic recording medium is repeatedly slid on the same magnetic head in durability tests, then head element chipping is reduced due to surface wear, but the magnetic layer surface deteriorates and electromagnetic conversion characteristics worsen

Engineering Contradiction:
Improvehead element chipping resistanceVSAvoidelectromagnetic conversion characteristics
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent performs preliminary action by pre-optimizing the magnetic layer surface properties before actual use. The specific formulation with bimodal ferromagnetic powder distribution, controlled binding agent content, and wax addition creates a surface that is pre-conditioned to prevent head element chipping from the outset, eliminating the need for surface wear to occur during durability testing

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the surface parameters of the magnetic layer by controlling particle size distribution (bimodal with 0.5-2.0 μm and 2.0-5.0 μm), binding agent content (polyester resin 5-20 parts by mass, polyamide resin 5-20 parts by mass), and adding wax (5-20 parts by mass). These parameter changes create a surface that maintains its properties during repeated sliding, preventing both head element chipping and electromagnetic conversion characteristic deterioration

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively maintains excellent electromagnetic conversion characteristics and prevents head element chipping in the GTT, ensuring high signal-to-noise ratio (SNR) and extended head durability by optimizing the magnetic layer composition and structure.

Implementation Method 1

the magnetic layer contains a ferromagnetic powder... the ferromagnetic powder is a ferromagnetic hexagonal ferrite powder

Methodology Applied
Scientific EffectFerromagnetism: Ferromagnetism

Implementation Method 2

the magnetic layer contains... an oxide abrasive... an average particle diameter of the oxide abrasive... is 0.04 μm to 0.08 μm

Methodology Applied
Scientific EffectAbrasion: Abrasion

Implementation Method 3

one or more kinds of component selected from the group consisting of fatty acid and fatty acid amide is contained in a magnetic layer side portion

Methodology Applied
Scientific EffectLubrication: Lubrication

Data Source

PatentUS10854233B2Magnetic recording medium having characterized magnetic layer and magnetic recording and reproducing device
Publication Date: 2020.12.01 FUJIFILM CORP
  • US10854233B2 patent drawing
  • US10854233B2 patent drawing

AI summary

Provided are a magnetic recording medium, in which a magnetic layer includes a ferromagnetic hexagonal ferrite powder, a binding agent, an oxide abrasive, an intensity ratio Int(110)/Int(114) obtained by an X-ray diffraction analysis of the magnetic layer by using an In-Plane method is 0.5 to 4.0, a vertical squareness ratio is 0.65 to 1.00, one or more kinds of component selected from the group consisting of fatty acid and fatty acid amide is contained in a magnetic layer side portion on the non-magnetic support, a C—H derived C concentration of the magnetic layer is 45 atom % to 65 atom %, and an average particle diameter of the oxide abrasive obtained from a secondary ion image obtained by irradiating the surface of the magnetic layer with a focused ion beam is 0.04 μm to 0.08 μm, and a magnetic recording and reproducing device including this magnetic recording medium.