Magnetic Repulsion Measurement of Adsorption in Diamagnetic Porous Materials

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Solution Overview

Problem

Current methods for determining the adsorption capacity of diamagnetic porous materials in liquid media are indirect and require specific analytical techniques for each analyte, limiting their applicability and accuracy.

Innovation Solution

A device utilizing opposing magnetic fields to measure the adsorption directly by detecting changes in the distance between a sample holder and an external magnet, correlating this change with the mass of adsorbed substances, independent of the chemical nature of the adsorbate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If indirect measurement methods are used to determine adsorption capacity in liquid media, then measurement can be performed, but the method depends on the analyte being completely soluble and requires specific analytical techniques for each analyte

Engineering Contradiction:
Improveapplicability to different analytesVSAvoidaccuracy of adsorption determination
Core Design Contradiction:
Adaptability or versatilityVSMeasurement precision

Solution Approach 1:

The patent replaces chemical analytical techniques (UV-Vis spectroscopy, NMR, chromatography) with a magnetic measurement system. The sample holder with permanent magnet interacts with an external magnet through magnetic field repulsion, converting chemical analysis into a physical measurement that is independent of the analyte's chemical properties, thereby achieving both universality and precision

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The magnetic measurement device is universally applicable to all diamagnetic porous materials and all analytes in liquid media. The same device and measurement principle can determine adsorption capacity for any substance dissolved in liquid, eliminating the need for multiple specific analytical techniques for different analytes

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Adaptability or versatility

If multiple analytical techniques are used to cover the variability of adsorbates, then measurement capability is expanded, but device complexity and cost increase

Engineering Contradiction:
Improvecoverage of different adsorbatesVSAvoidnumber of measurement techniques and equipment
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent creates a single universal device that can measure adsorption capacity for any diamagnetic porous material and any analyte in liquid media. The magnetic field-based measurement system replaces the need for multiple specialized techniques (UV-Vis, NMR, chromatography), thereby reducing device complexity while maintaining broad adaptability

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The measurement relies on changing the magnetic field parameters (strength, orientation) rather than requiring different analytical methods. By adjusting the external magnet's position and strength, the system can accommodate different adsorbate concentrations and types, achieving versatility through parameter adjustment rather than equipment multiplication

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If direct determination of adsorption is achieved, then measurement simplicity is improved, but the device requires precise control of magnetic field interaction

Engineering Contradiction:
Improvesimplicity of adsorption measurementVSAvoidprecision requirements of magnetic field control
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent replaces complex chemical analysis procedures with a straightforward magnetic measurement. The sample holder with permanent magnet is positioned relative to an external magnet, and the distance between them is measured. This mechanical/geometric measurement is simpler to operate than chemical analysis, and the precision requirement is managed through standard measurement techniques rather than complex field control

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables direct and universal measurement of adsorption in any liquid medium, eliminating the need for specific calibration and analytical techniques for each adsorbate, and providing a simple, portable, and non-destructive method for measuring adsorption isotherms and kinetics.

Implementation Method 1

One of the magnets supports the sample-holder submerged within the liquid through the repulsion force established with an external magnet with opposite pole orientation

Methodology Applied
Scientific EffectMagnetic repulsion: Magnetism

Data Source

PatentEP4636386A1Device and method for measuring the capacity of diamagnetic porous materials to capture substances dissolved in a liquid medium
Publication Date: 2025.10.22 UNIV DEL PAIS VASCO EUSKAL HERRIKO UNIBERTSITATEA
  • EP4636386A1 patent drawingFigure 1
  • EP4636386A1 patent drawingFigure 2~3B
  • EP4636386A1 patent drawingFigure 4

AI summary

The invention relates to a device for measuring the capacity of diamagnetic porous materials to capture substances dissolved in a liquid medium. The device comprises: a sample holder containing a diamagnetic porous material, and an adsorbate captured in the pores of the diamagnetic material, a sample holder permanent magnet attached to the lower base of the sample-holding container, a receptacle inside which the container and the sample holder permanent magnet are housed in liquid suspension, and an external permanent magnet aligned vertically with the sample holder permanent magnet. The two magnets generate magnetic fields aligned vertically and facing each other, to float the sample-holding container, so that the separation distance between the sample holder permanent magnet and the external magnet or the electromagnet depends on the mass supported by the sample holder permanent magnet.