Magnetic Thermosetting Composition for Uniform Internal Curing

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional 3D printing methods using thermosetting and photocurable resins face issues such as imprecise shape, non-uniform curing, phase separation, and low hardness due to equipment limitations and heat-related problems, particularly with the use of magnetic composite materials.

Innovation Solution

A thermosetting composition utilizing magnetic particles with multiple domains that generate vibrational heat under an external magnetic field for uniform curing, avoiding eddy currents and hysteresis losses, ensuring stable and precise curing of the resin.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If electromagnetic induction heating is used to cure thermosetting resin, then curing speed is improved, but temperature difference between contact surface and inside is generated causing non-uniform curing

Engineering Contradiction:
Improvecuring speedVSAvoidcuring uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent uses magnetic particles with multi-magnetic domains that generate vibrational heat through magnetization reversal under an external magnetic field. This vibrational heating mechanism produces uniform heat distribution throughout the resin without the temperature gradients characteristic of conventional electromagnetic induction heating, thereby achieving both fast curing speed and uniform curing quality.

Inventive Principle:
Principle #18Mechanical vibration

2Power

If conventional electromagnetic induction heating is used, then heat generation efficiency is improved, but hysteresis loss occurs reducing curing quality

Engineering Contradiction:
Improveheat generation efficiencyVSAvoidhysteresis loss
Core Design Contradiction:
PowerVSLoss of energy

Solution Approach 1:

The patent changes the key parameter of magnetic particle size to the nanometer range (1-100 nm), which fundamentally alters the heating mechanism. At this scale, hysteresis loss becomes negligible and eddy current effects are minimized, allowing heat generation primarily through vibrational mechanisms. This parameter change enables efficient heat generation without the energy losses associated with conventional electromagnetic induction heating.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If photocurable resin is used for 3D printing, then shape precision is improved, but equipment size and storage requirements increase

Engineering Contradiction:
Improveshape precisionVSAvoidequipment size
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces the photocuring mechanism (which requires complex UV light sources and optical systems) with a magnetic field-based vibrational heating mechanism. This substitution eliminates the need for large-scale optical equipment while achieving precise curing control through magnetic field application, thereby maintaining shape precision while reducing equipment complexity and size.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Ease of manufacture

If thermosetting resin is cured by conventional heating, then process simplicity is improved, but heat shrinkage and phase separation occur

Engineering Contradiction:
Improveprocess simplicityVSAvoidphase separation
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent employs vibrational heating through magnetic particle oscillation to cure the thermosetting resin. This vibrational energy promotes uniform heat distribution and molecular mobility during curing, preventing phase separation between organic and inorganic components while avoiding the heat shrinkage problems associated with conventional thermal heating methods.

Inventive Principle:
Principle #18Mechanical vibration

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves uniform and stable curing of the thermosetting resin, enhancing the physical properties of the cured product by controlling the coercive force and saturation magnetization of the magnetic particles, reducing hysteresis loss and ensuring excellent mechanical properties.

Implementation Method 1

The present application generates vibrational heat by magnetization reversal of magnetic particles through electromagnetic induction heating

Methodology Applied
Scientific EffectElectromagnetic induction heating: Electromagnetic Induction

Implementation Method 2

vibrational heat is generated from the magnetic particles through the application of a magnetic field to the composition

Methodology Applied
Scientific EffectVibrational heat: Vibration

Implementation Method 3

be magnetized by an external alternate-current magnetic field. Here, the irregular arrangement of the magnetic domains may mean a state where magnetic directions existing in the magnetic domains are each different and not aligned, and in this case, may be a state without magnetism as the net value of the magnetization at room temperature is zero. However, when an external magnetic field is applied, the magnetic directions of the magnetic domains are aligned, whereby the magnetic particles can be magnetized

Methodology Applied
Scientific EffectMagnetization: Magnetism

Implementation Method 4

a thermosetting resin, and magnetic particles... In the curing method according to the present application, vibrational heat is generated from the magnetic particles through the application of a magnetic field to the composition, whereby the entire thermosetting resin can be uniformly cured

Methodology Applied
Scientific EffectThermosetting curing: Chemical Bonding

Data Source

PatentUS11872623B2Thermosetting composition
Publication Date: 2024.01.16 LG CHEM LTD

AI summary

The present invention relates to a thermosetting composition and a method for curing the same, and provides a thermosetting composition capable of realizing uniform curing physical properties of a cured product.