Magnetic Toner Surface Coverage for Ghosting Reduction

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Solution Overview

Problem

Existing magnetic toners suffer from ghosting issues, particularly in low-humidity environments, due to charge differences between freshly supplied and residual toner, leading to image density irregularities and poor image quality.

Innovation Solution

A magnetic toner comprising a binder resin, magnetic body, and inorganic fine particles such as silica, alumina, and titania, with specific coverage ratios and particle distributions to enhance charge uniformity and reduce electrostatic aggregation, ensuring high image density and ghosting-free output across varying environments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If external additives like alumina or titania are added to improve flowability and aggregative property, then toner transportability is improved, but ghosting worsens in low-humidity environments

Engineering Contradiction:
Improvetoner transportabilityVSAvoidimage quality stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The invention changes the particle size parameter of external additives to specifically 5 nm or smaller, and controls the coverage ratio to 3-15 parts by mass per 100 parts by mass of toner. This parameter optimization resolves the contradiction by maintaining transportability while preventing excessive charge accumulation that causes ghosting in low-humidity environments.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite inorganic fine particles comprising silica and at least one of alumina or titania. This composite structure combines the flowability enhancement of alumina/titania with the charge control properties of silica, achieving both good transportability and reduced ghosting through synergistic material combination.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If external additives are added to reduce electrostatic aggregation, then charge uniformity improves, but image density and ghosting performance become inadequate in low-humidity environments

Engineering Contradiction:
Improvecharge uniformityVSAvoidghosting resistance
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The invention optimizes the particle size parameter to 5 nm or smaller, which is small enough to distribute uniformly and stabilize charge, yet small enough to not cause excessive charge accumulation. The coverage ratio is controlled at 3-15 parts by mass per 100 parts by mass of toner, balancing charge uniformity with ghosting resistance in low-humidity conditions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies external additives selectively on the toner surface at a controlled coverage ratio (3-15 parts by mass per 100 parts by mass of toner). This localized application ensures sufficient charge uniformity while preventing excessive charge accumulation that would cause ghosting, achieving local optimization of both properties.

Inventive Principle:
Principle #3Local quality

3Stability of the object's composition

If inorganic fine particles are added to improve charge uniformity, then ghosting is reduced, but toner flowability and transportability deteriorate

Engineering Contradiction:
Improvecharge uniformityVSAvoidtoner flowability
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The invention optimizes the particle size parameter to 5 nm or smaller, which maintains toner flowability by preventing excessive aggregation. The coverage ratio is controlled at 3-15 parts by mass per 100 parts by mass of toner, providing sufficient charge uniformity without excessive additive content that would harm flowability. This parameter optimization resolves the contradiction between charge uniformity and flowability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses homogeneous inorganic fine particles with uniform particle size distribution (5 nm or smaller) and controlled coverage ratio. This homogeneity ensures consistent charge distribution across toner particles while maintaining uniform flow characteristics, preventing both charge irregularities and flowability deterioration.

Inventive Principle:
Principle #33Homogeneity

4Manufacturing precision

If coverage ratio of external additives is increased to improve image density, then charge uniformity improves, but ghosting worsens due to excessive charge accumulation

Engineering Contradiction:
Improveimage densityVSAvoidghosting resistance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The invention optimizes the coverage ratio parameter to 3-15 parts by mass per 100 parts by mass of toner, which is sufficient to achieve high image density through improved charge uniformity, yet low enough to prevent excessive charge accumulation that causes ghosting. This parameter optimization resolves the contradiction between image density and ghosting resistance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively inhibits electrostatic aggregation and enhances charge uniformity, resulting in high image density and reduced ghosting, regardless of environmental conditions, by optimizing the coverage ratios and distribution of inorganic fine particles on the toner surface.

Implementation Method 1

inorganic fine particles present on the surface of the magnetic toner particles comprise silica fine particles and at least one of alumina fine particles and titania fine particles

Methodology Applied
Scientific EffectDielectric: Dielectric

Data Source

PatentUS9235151B2Magnetic toner
Publication Date: 2016.01.12 CANON KK
  • US9235151B2 patent drawing
  • US9235151B2 patent drawing
  • US9235151B2 patent drawing

AI summary

A magnetic toner containing: magnetic toner particles containing a binder resin and a magnetic body; and inorganic fine particles, as described in the specification, present on the surface of the magnetic toner particles. A coverage ratio A of the magnetic toner particles' surface by the inorganic fine particles, as described in the specification, and a coverage ratio B of the magnetic toner particles' surface by the inorganic fine particles each of which is fixed to the magnetic toner particles' surface, as described in the specification, have prescribed values and a prescribed relationship in the magnetic toner. The alumina fine particles and/or titania fine particles are present on the surface of the magnetic toner particles as described in the specification.