Mn-based Ferrite Carrier Particles for High-Speed Electrophotography

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Solution Overview

Problem

In electrophotographic image formation devices, increasing the speed of image formation often results in insufficient image density when using carriers with small-diameter particles, as they fail to effectively supply toner to the photoconductive member.

Innovation Solution

Ferrite particles with a composition formula Mn_xFe3-xO4, containing 0.1 to 2.5 weight percent of Sr or Ca elements, exhibit a fluidity of 40 seconds or more under a magnetic field, allowing for enhanced movement within the development region and increased toner transfer, thereby achieving higher image density.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the speed of image formation is increased, then productivity is improved, but image density deteriorates when using carriers with small-diameter particles

Engineering Contradiction:
Improveimage formation speedVSAvoidimage density
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The invention changes the physical and chemical parameters of the carrier particles by incorporating specific amounts of Sr or Ca elements (0.1 to 2.5 weight%) into the Mn-based ferrite structure. This modifies the fluidity parameter to 40 seconds or more, which enables the carrier to maintain effective toner supply capability even at high image formation speeds, thereby resolving the contradiction between productivity and image density

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite carrier particle structure by combining Mn-based ferrite with Sr or Ca elements. This composite material approach results in a carrier with optimized magnetic properties and fluidity characteristics, enabling simultaneous achievement of high-speed image formation and sufficient image density that cannot be obtained with conventional single-component carriers

Inventive Principle:
Principle #40Composite materials

2Productivity

If carriers with small-diameter particles are used, then the amount of developer supplied per unit time is increased, but toner supply to photoconductive member becomes insufficient

Engineering Contradiction:
Improveamount of developer supplied per unit timeVSAvoidtoner supply amount
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The invention changes the fluidity parameter of the carrier particles to 40 seconds or more by incorporating Sr or Ca elements. This parameter change enables small-diameter carrier particles to maintain sufficient toner supply capability, resolving the contradiction between increasing developer supply rate and maintaining adequate toner transfer to the photoconductive member

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ferrite particles ensure sufficient image density even at increased image formation speeds by enhancing the circulation and agitation of toner within the development region, improving the coupling and frictional resistance of the carrier particles, which leads to effective toner distribution on the photoconductive member.

Implementation Method 1

a magnetic brush in which the carriers are aggregated and its bristles are raised is formed on the development sleeve and a development bias voltage is applied between the photoconductive member and the development sleeve

Methodology Applied
Scientific EffectMagnetic field: Magnetic Field

Implementation Method 2

ferrite particles with a composition formula Mn_xFe3-xO4, containing 0.1 to 2.5 weight percent of Sr or Ca elements, exhibit a fluidity of 40 seconds or more under a magnetic field

Methodology Applied
Scientific EffectMagnetism: Magnetism

Implementation Method 3

improving the coupling and frictional resistance of the carrier particles, which leads to effective toner distribution on the photoconductive member

Methodology Applied
Scientific EffectFriction: Friction

Data Source

PatentEP2690499B1Ferrite particles, electrophotography carrier using same, and electrophotography developer
Publication Date: 2017.06.14 DOWA ELECTRONICS MATERIALS CO LTD
  • EP2690499B1 patent drawingFigure 1~2

AI summary

A material expressed as a composition formula MxFe3-xO4 (where M is at least one of Mg and Mn, and 0 ≤ X ≤ 1) is a main component, and as a total amount, 0.1 to 2.5 weight percent of at least one of a Sr element and a Ca element is contained. Here, when ferrite particles are used as a carrier, in terms of obtaining a higher image density, the fluidity of the ferrite particles magnetized under a magnetic field of 1000/(4π) kA/m (1000 oersteds) is preferably 40 seconds or more. The residual magnetization σr is preferably 3 Am2/kg or more.