Lithographic Mask Surface Processing via Segmented Gas Exposure

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Solution Overview

Problem

Existing methods for processing lithographic masks struggle to selectively optimize exposure settings and process parameters for partial reactions without negatively affecting other processes, due to the use of gas mixtures that promote multiple reactions simultaneously.

Innovation Solution

A method involving a gas mixture with a first and second gas, where the reaction site is exposed to energetic particles in multiple intervals with a gas refresh interval to selectively amplify one partial reaction's process rate relative to another, by adjusting the gas refresh interval and exposure parameters.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If gas mixtures are used to promote multiple partial reactions simultaneously, then productivity is improved by processing multiple defects in one cycle, but manufacturing precision deteriorates because exposure settings cannot be selectively optimized for individual partial reactions

Engineering Contradiction:
Improveprocessing throughputVSAvoidprocess parameter optimization precision
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent segments the processing cycle into multiple distinct exposure intervals, each dedicated to optimizing a specific partial reaction. Between these intervals, gas refresh intervals supply different reaction gases selectively. This temporal segmentation allows each partial reaction to be optimized independently while maintaining high overall productivity through continuous processing.

Inventive Principle:
Principle #1Segmentation

2Manufacturing precision

If gas refresh intervals are introduced to selectively promote partial reactions, then manufacturing precision is improved by optimizing exposure settings for specific reactions, but productivity deteriorates due to additional time intervals between exposures

Engineering Contradiction:
Improvepartial reaction optimizationVSAvoidprocessing cycle time
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent implements periodic action by alternating between exposure intervals and gas refresh intervals in a cyclic manner. Each exposure interval is optimized for a specific partial reaction, followed by a gas refresh interval that prepares the reaction environment for the next exposure. This periodic structure enables selective optimization while maintaining continuous processing flow.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

Gas refresh intervals perform preliminary action by supplying and adsorbing the appropriate reaction gas before each exposure interval. This ensures that when each exposure interval begins, the reaction environment is already optimized for the intended partial reaction, eliminating the need for separate gas introduction steps during exposure and thereby minimizing time penalties.

Inventive Principle:
Principle #10Preliminary action

3Device complexity

If multiple reaction gases are supplied simultaneously as a mixture, then device complexity is reduced by using a single gas supply system, but adaptability deteriorates because individual gas concentrations cannot be independently controlled

Engineering Contradiction:
Improvegas supply system complexityVSAvoidprocess parameter control flexibility
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The patent introduces dynamics by switching gas supply configurations between different time intervals. During gas refresh intervals, the system dynamically introduces specific reaction gases with controlled concentrations. During exposure intervals, the gas supply is maintained at levels optimized for the active partial reaction. This dynamic adjustment of gas concentrations across time enables high adaptability while using a relatively simple gas supply infrastructure.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for targeted optimization of process rates and parameters for specific partial reactions, enabling more precise control over mask repair and surface processing in microelectronics, enhancing the accuracy and efficiency of defect correction.

Implementation Method 1

By exposure to an energetic particle beam, the adsorbed gas molecules can be 'activated'

Methodology Applied
Scientific EffectPhotoactivation: Photoionisation

Implementation Method 2

These reaction gases then diffuse to the reaction site and are adsorbed here at the surface of the mask

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

the first partial reaction is promoted primarily by the first gas and the second partial reaction is promoted primarily by the second gas

Methodology Applied
Scientific EffectSelective chemical reaction: Chemical Bonding

Implementation Method 4

These reaction gases then diffuse to the reaction site and are adsorbed here at the surface of the mask

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS20240118632A1Method, apparatus and computer program for processing a surface of an object
Publication Date: 2024.04.11 CARL ZEISS SMT GMBH
  • US20240118632A1 patent drawing
  • US20240118632A1 patent drawing

AI summary

Described are a method for processing a surface of an object, in particular of a lithographic mask, an apparatus for carrying out such a method and a computer program containing instructions for carrying out such a method.A method for processing a surface of an object, in particular of a lithographic mask, includes the following steps: (a.) supplying a gas mixture containing at least a first gas and a second gas to a reaction site at the surface of the object; (b.) inducing a reaction, which includes at least a first partial reaction and a second partial reaction, at the reaction site by exposing the reaction site to a beam of energetic particles in a plurality of exposure intervals, wherein the first partial reaction is promoted primarily by the first gas and the second partial reaction is promoted primarily by the second gas, and wherein a gas refresh interval lies between the respective exposure intervals; (c.) setting a first time duration for the gas refresh interval, as a result of which the process rate of the first partial reaction and the process rate of the second partial reaction are present; (d.) setting a second time duration for the gas refresh interval, which brings about a relative increase in the process rate of the first partial reaction in comparison with the process rate of the second partial reaction.