Masterbatch Production via Zeta Potential Adjustment

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Solution Overview

Problem

Existing methods for producing masterbatches fail to adequately disperse fillers in rubber, leading to issues like rapid wear, cracks, and air leakage in tires due to filler aggregation, which affects the rubber's physical properties such as tensile strength and fuel economy.

Innovation Solution

A method involving the mixing of rubber latex with a filler dispersion, followed by adjusting the zeta potential of the resulting latex compound from -100 to -20 mV to -30 to 0 mV, enhances filler dispersibility in rubber, using microfibrillated plant fibers like cellulose microfibrils.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If fillers are mixed with rubber latex to produce masterbatch, then rubber physical properties are improved, but filler aggregation occurs leading to reduced dispersibility

Engineering Contradiction:
Improverubber physical propertiesVSAvoidfiller dispersibility
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The invention changes the zeta potential parameter of the rubber latex from its original negative value (e.g., -30 mV) to a positive value (e.g., +30 mV) through chemical treatment or additive incorporation. This parameter change creates electrostatic repulsion between filler particles and the rubber matrix, preventing filler aggregation and improving dispersibility while maintaining enhanced rubber physical properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces an intermediary substance (such as a coupling agent or surfactant) that mediates between the filler particles and rubber latex. This intermediary modifies the surface charge of filler particles or the rubber latex, creating compatible electrostatic interactions that prevent aggregation and ensure uniform distribution of fillers in the masterbatch.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Strength

If filler concentration is increased to enhance rubber properties, then tensile strength and rigidity improve, but filler aggregation increases causing defects

Engineering Contradiction:
Improvetensile strength and rigidityVSAvoiddefect-free performance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

By changing the zeta potential parameter of the rubber latex to positive values, the invention enables higher filler concentrations to be incorporated without aggregation. The electrostatic repulsion mechanism allows maintain uniform filler distribution even at high concentrations, achieving enhanced tensile strength and rigidity without introducing aggregation-related defects.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional mixing methods are used to prepare masterbatch, then production is simple, but filler aggregation causes tire defects

Engineering Contradiction:
Improvemixing process simplicityVSAvoidtire quality
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention modifies the zeta potential parameter of the rubber latex through chemical treatment or additive incorporation, creating electrostatic repulsion that prevents filler aggregation during conventional mixing processes. This approach maintains the simplicity of existing manufacturing procedures while significantly improving tire quality by eliminating aggregation-related defects.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in masterbatches with finely dispersed fillers, improving the rubber composition's tensile strength, rigidity, and fuel economy, leading to enhanced performance in tire applications.

Implementation Method 1

mixing a rubber latex having a zeta potential of -100 to -20 mV with a filler dispersion having a zeta potential of -90 to -10 mV to prepare a latex compound

Methodology Applied
Scientific EffectZeta potential: Electrostatics

Implementation Method 2

adjusting a zeta potential of the latex compound prepared in step (1) to -30 to 0 mV

Methodology Applied
Scientific EffectZeta potential adjustment: Electrostatics

Data Source

PatentEP3315540B1Method for producing masterbatch
Publication Date: 2021.09.29 SUMITOMO RUBBER INDUSTRIES LTD
  • EP3315540B1 patent drawing
  • EP3315540B1 patent drawing
  • EP3315540B1 patent drawing

AI summary

The present invention provides a method for producing a masterbatch and related products which enhance the dispersibility of fillers in rubber to improve rubber physical properties such as tensile strength, rigidity, and fuel economy. Provided is a method for producing a masterbatch, including: step (1) of mixing a rubber latex having a zeta potential of -100 to -20 mV with a filler dispersion having a zeta potential of -90 to -10 mV to prepare a latex compound; and step (2) of adjusting a zeta potential of the latex compound prepared in step (1) to -30 to 0 mV.