Matte Paint Microsphere Composition for Stain Blocking Balance

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Solution Overview

Problem

Matte paints with low gloss suffer from reduced durability and resistance due to high pigment volume concentration, making it difficult to achieve a balance between stain blocking and stain removal properties.

Innovation Solution

A composition comprising an aqueous dispersion of polymer particles, anion exchange resin particles, and non-film-forming polymeric microspheres with specific size and thermal properties, providing a balanced stain blocking and stain removal performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If high pigment volume concentration of inorganic extenders is used in matte paints, then matte finish is achieved, but durability and resistance properties are reduced

Engineering Contradiction:
Improvematte finishVSAvoiddurability and resistance
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The invention changes the particle size parameter of polymer particles to submicron range (50-500 nm) and controls pigment volume concentration within specific ranges to achieve matte finish while maintaining durability. This parameter optimization resolves the contradiction by finding the optimal balance point where both matte appearance and coating integrity are preserved.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite coating system combining submicron polymer particles, micron-sized polymer beads, and inorganic extenders in specific weight ratios. This composite approach allows the different components to work synergistically - the polymer particles provide film formation and adhesion, while the controlled inextender concentration provides matte finish, resolving the contradiction between appearance and durability.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If stain blocking property is improved, then stain removal property is compromised, and vice versa

Engineering Contradiction:
Improvestain blockingVSAvoidstain removal
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The invention applies local quality by incorporating micron-sized polymer beads (1-20 μm) with different properties than the submicron particles. These beads are specifically sized to remain on surface irregularities and provide localized stain blocking at defect sites, while the submicron polymer particles form a continuous film that maintains overall stain removal capability. This spatial differentiation of particle functions resolves the orthogonal contradiction.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention segments the coating system into two distinct particle size populations - submicron polymer particles (50-500 nm) for continuous film formation and stain removal, and micron-sized polymer beads (1-20 μm) for localized stain blocking. This segmentation allows each component to specialize in one function without compromising the other, resolving the contradiction between stain blocking and stain removal properties.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves an excellent balance of stain blocking and stain removal properties in matte paints, enhancing durability without compromising stain removal performance.

Implementation Method 1

b) from 0.01 to 7 weight percent, based on the weight the polymer particles, of anion exchange resin particles

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Implementation Method 2

The composition of the present invention is useful for paint compositions that form matte finishes with an excellent balance of stain blocking and stain removal properties

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentEP4048742B1Aqueous composition of organic polymeric microspheres, binder particles, and ion exchange resin
Publication Date: 2026.03.11 ROHM & HAAS CO
  • EP4048742B1 patent drawing
  • EP4048742B1 patent drawing
  • EP4048742B1 patent drawing

AI summary

The present invention relates to a composition comprising an aqueous dispersion of a) polymer particles having a z- average particle size in the range of from 50 nm to 500 nm; b) anion exchange resin particles having a D50 median particle size in the range of from 0.1 μm to 50 μm; and c) polymeric organic microspheres having a D50 median particle size in the range of from 1 μm to 20 μm, wherein the weight-to-weight ratio of polymer particles to microspheres is in the range of from 0.5:1 to 20:1. The composition of the present invention is useful for paint compositions that form matte finishes with an excellent balance of stain blocking and stain removal properties.