Microcrystalline Cellulose and Calcium Phosphate Blend for Tablet Recompaction

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Solution Overview

Problem

Existing pharmaceutical binders face challenges in achieving adequate recompactibility across a wide range of tabletting pressures without compromising other desirable properties, such as flow characteristics and sensitivity to lubricant presence, which affects the production of solid dosage forms like tablets.

Innovation Solution

A physical blend of microcrystalline cellulose and anhydrous calcium phosphate particles with a median particle size of not greater than 20 microns, specifically 10 microns, is used to enhance recompactibility, reducing the need for additional excipients and improving tensile strength of granules and tablets.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional binders are used to achieve adequate recompactibility, then recompactibility is improved, but flow characteristics deteriorate or sensitivity to lubricant presence increases

Engineering Contradiction:
ImproverecompactibilityVSAvoidflow characteristics
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent applies composite materials by combining microcrystalline cellulose (MCC) and anhydrous calcium phosphate (CaP) in a physical blend. This composite excipient maintains good flow characteristics from MCC while gaining improved recompactibility from the fine particle size CaP (median not greater than 20 microns), resolving the contradiction between recompactibility and flow properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the particle size parameter of calcium phosphate to a median not greater than 20 microns, which significantly improves recompactibility. This parameter change allows the CaP to function as an effective binder in roller compaction while maintaining compatibility with lubricants and preserving flow characteristics when blended with MCC.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If binder concentration is increased to improve recompactibility, then recompactibility is improved, but manufacturing cost increases

Engineering Contradiction:
ImproverecompactibilityVSAvoidbinder concentration
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The physical blend of MCC and anhydrous CaP creates a composite excipient where the fine particle size CaP provides binding functionality at lower concentrations. This reduces the overall quantity of binder needed compared to conventional binders, lowering manufacturing costs while maintaining adequate recompactibility.

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If multiple compaction steps are used (roller compaction followed by tabletting), then granulation quality is improved, but process complexity increases

Engineering Contradiction:
Improvegranulation qualityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent changes the particle size parameter of calcium phosphate to median not greater than 20 microns, which significantly improves recompactibility. This parameter change allows the CaP to function as an effective binder in roller compaction while maintaining compatibility with lubricants and preserving flow characteristics when blended with MCC.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The blend provides improved recompactibility, reduced friability, and enhanced resistance to physical handling, leading to higher yields and fewer defective tablets, while minimizing the use of extragranular excipients and lowering manufacturing costs.

Implementation Method 1

a physical blend of particles of at least one calcium phosphate and particles of microcrystalline cellulose, wherein the particles of at least one calcium phosphate have an median (D50) particle size as measured by laser diffraction of not greater than about 20 microns

Methodology Applied
Scientific EffectDry blending:

Implementation Method 2

an median (D50) particle size as measured by laser diffraction of not greater than about 20 microns

Methodology Applied
Scientific EffectLaser diffraction: Diffraction

Implementation Method 3

the resulting material milled to uniform size

Methodology Applied
Scientific EffectMilling: Abrasion

Data Source

PatentEP2498818B8Microcrystalline cellulose and calcium phosphate compositions useful as pharmaceutical excipients
Publication Date: 2018.03.21 FMC CORP

AI summary

Compositions containing calcium phosphate and microcrystalline cellulose are useful as excipients in the preparation of solid dosage forms containing active pharmaceutical ingredients, particularly those prepared by processes involving multiple compaction steps. The recompactibility performance of such compositions is improved through the use of calcium phosphate having a relatively small particle size, e.g., a median particle size of not more than about 20 microns or not more than about 10 microns.