MCrAlY Coating Thermal Expansion Mismatch Reduction

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Solution Overview

Problem

Current metallic coatings for high temperature gas turbine engine components face challenges in balancing fatigue resistance and oxidation resistance, with diffused aluminides providing inadequate high temperature protection and MCrAlY coatings suffering from tensile internal stress and thermal expansion mismatch.

Innovation Solution

A low-cost metallic coating composition with specific weight percentages of cobalt, chromium, aluminum, yttrium, hafnium, silicon, zirconium, tantalum, tungsten, molybdenum, and platinum, applied using techniques like cathodic arc plasma vapor deposition, which reduces thermal expansion mismatch and enhances oxidation and fatigue resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If diffused aluminide coatings are used, then fatigue resistance is improved, but high temperature oxidation resistance deteriorates

Engineering Contradiction:
Improvefatigue resistanceVSAvoidoxidation resistance
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses a composite coating structure with multiple layers: a diffused aluminide base layer providing fatigue resistance, an intermediate MCrAlY layer, and an overlay coating with active elements (yttrium, hafnium, silicon) on top. This composite structure combines the advantages of both coating types while mitigating their individual disadvantages.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Different regions of the coating have different compositions and functions. The diffused aluminide layer provides fatigue resistance at the substrate interface, the intermediate layer provides transition and oxidation protection, while the overlay layer provides enhanced oxidation resistance at the surface. Each layer is optimized for its specific function.

Inventive Principle:
Principle #3Local quality

2Object-affected harmful factors

If overlay MCrAlY coatings are used, then high temperature oxidation resistance is improved, but fatigue resistance deteriorates due to tensile internal stress

Engineering Contradiction:
Improveoxidation resistanceVSAvoidfatigue resistance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The multi-layer composite structure distributes stress more evenly. The diffused aluminide base layer has compressive stress that counteracts the tensile stress in the overlay layer, reducing net tensile stress and improving fatigue resistance while maintaining oxidation protection.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the composition and thickness parameters of each layer to optimize stress distribution. By controlling the aluminum content in the diffused layer and the thickness of the intermediate layer, the overall stress state is adjusted to reduce tensile stress while maintaining oxidation resistance.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If refractory metals are added to improve oxidation resistance, then coating performance is improved, but manufacturing cost increases

Engineering Contradiction:
Improveoxidation resistanceVSAvoidcoating cost
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

Active elements (yttrium, hafnium, silicon) are concentrated in the overlay layer where they are most needed for oxidation resistance, rather than distributing them throughout the entire coating. This localized placement maximizes performance while minimizing material cost.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses smaller amounts of expensive refractory elements compared to conventional coatings, replacing some with more cost-effective elements like silicon and aluminum that can provide similar oxidation protection when properly configured in the multi-layer structure.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating composition provides improved oxidation and fatigue resistance, reducing thermal expansion mismatch and promoting uniform oxide growth kinetics, thus extending the lifespan of turbine engine components.

Implementation Method 1

reduces the thermal expansion mismatch between the coating and common turbine alloys

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 2

a thermally grown oxide of alumina is grown between the bond coat and the TBCs topcoat

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

promoting uniform oxide growth kinetics

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 4

a thermally grown oxide of alumina is grown between the bond coat and the TBCs topcoat

Methodology Applied
Scientific EffectThermal growth: Heat Treatment

Data Source

PatentUS9382605B2Economic oxidation and fatigue resistant metallic coating
Publication Date: 2016.07.05 RTX CORP
  • US9382605B2 patent drawing

AI summary

The present disclosure relates to an improved low-cost metallic coating to be deposited on gas turbine engine components. The metallic coating consists of 1.0 to 18 wt % cobalt, 3.0 to 18 wt % chromium, 5.0 to 15 wt % aluminum, 0.01 to 1.0 wt % yttrium, 0.01 to 0.6 wt % hafnium, 0.0 to 0.3 wt % silicon, 0.0 to 1.0 wt % zirconium, 0.0 to 10 wt % tantalum, 0.0 to 9.0 wt % tungsten, 0.0 to 10 wt % molybdenum, 0.0 to 43.0 wt % platinum, and the balance nickel.