MDO Multilayer Film Sealant Layer Design

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Solution Overview

Problem

Machine direction oriented (MDO) polyethylene films experience significant loss of sealing performance and reduced temperature resistance, leading to a narrow sealing window, making it challenging to manufacture articles requiring heat sealing.

Innovation Solution

A multilayer structure comprising a MDO film with a metal layer, a first layer extruded onto the metal layer, and a sealant layer in adhering contact, where the first layer includes an interpolymer of ethylene and acrylic acid or methacrylic acid, and the sealant layer has a heat seal initiation temperature of 95°C or less, allowing for reduced sealing temperatures and broader sealing windows.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If MDO polyethylene films are used to achieve orientation and mechanical properties, then sealing performance is significantly lost and temperature resistance is reduced, but this results in a very narrow sealing window and manufacturing challenges

Engineering Contradiction:
Improvesealing performanceVSAvoidsealing window
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The film is divided into multiple functional layers: an MDO polyethylene layer providing mechanical strength and orientation, and a separate sealant layer providing sealing capability. This segmentation allows each layer to optimize its specific function without compromising the other, resolving the contradiction between maintaining MDO structural integrity and achieving reliable sealing performance

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite structure combining MDO polyethylene film with a sealant layer having complementary properties. The sealant layer is specifically selected or formulated to have appropriate melt temperature and sealing characteristics that the MDO polyethylene layer lacks, creating a composite material system that achieves both mechanical strength and sealing performance

Inventive Principle:
Principle #40Composite materials

2Reliability

If sealing temperature is increased to compensate for MDO film degradation, then sealing performance improves, but degradation and burning of other layers increases

Engineering Contradiction:
Improvesealing consistencyVSAvoiddegradation and burning
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The sealant layer acts as an intermediary between the heat source and the MDO polyethylene layers. It is specifically designed to melt and seal at a lower temperature than the MDO layers would degrade, thereby mediating the sealing process to protect the structural layers from thermal damage while still achieving reliable seals

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the thermal parameters of the sealing system by introducing a sealant layer with a lower melt temperature and appropriate sealing characteristics. This parameter change allows sealing to occur at temperatures that prevent degradation of the MDO polyethylene structure, resolving the contradiction between sealing reliability and thermal damage

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If a sealant layer with low seal initiation temperature is added, then sealing window broadens and degradation is reduced, but device complexity increases

Engineering Contradiction:
Improvesealing window rangeVSAvoidmultilayer structure
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The sealing function is segmented into a dedicated sealant layer that can be independently selected and optimized. This layer is specifically chosen for its low seal initiation temperature and appropriate rheological properties, allowing the rest of the MDO structure to maintain its structural integrity while achieving broad sealing window adaptability

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The sealant layer serves multiple functions: it provides the primary sealing interface, protects underlying layers from thermal degradation, and broadens the sealing window. This multi-functionality justifies the added layer complexity by consolidating multiple benefits into a single component

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enables consistent sealing at lower temperatures, reducing degradation of the multilayer structure and expanding the sealing and shrinkage range, thereby improving manufacturing efficiency and product integrity.

Implementation Method 1

the sealant layers of both films are in contact with each other, the seal bars contact and heat the outer layers of the films. The heat is transferred through the outer layers of the films to the inner sealant layers which seal to one another

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Implementation Method 2

The interpolymer may have a melt index (I2) of 5 to 20 g/10 minutes, an acid content of 1 to 10 weight percent and a melting temperature of 90° C. to 100° C.

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentUS20240336044A1Multilayer structures that include machine direction oriented multilayer films
Publication Date: 2024.10.10 DOW GLOBAL TECHNOLOGIES LLC

AI summary

In one embodiment, a multilayer structure may include a machine direction oriented (MDO) multilayer film, a first layer, and a sealant layer. The MDO multilayer film may include (i) a metal layer and (ii) an inner layer. The inner layer may include EVOH: PVOH: or a blend of polyethylene and an interpolymer of ethylene and methyl acrylate, ethyl acrylate, or carboxylic acid. The first layer may be extruded onto the metal layer. The first layer may include an interpolymer of ethylene and acry lic acid or methacrylic acid. The interpolymer may have a melt index (12) of 5 to 20 g/10 minutes. an acid content of 1 to 10 weight percent and a melting temperature of 90° C. to 100° C. The sealant layer may include a polyethylene having a melt index (I2) of 3 to 30 g/10 minutes and a heat seal initiation temperature of 95° C. or less.