Membrane Electrode Assembly Edge Sealing Without Active Area Loss

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Solution Overview

Problem

The existing method of laminating a membrane electrode assembly for fuel cells results in approximately 6% of the active surface being covered by adhesive, leading to performance degradation and increased costs.

Innovation Solution

Applying a sealant and/or adhesive only to the end faces of the membrane, forming a gas barrier and bond with plastic films, while keeping the active surfaces adhesive-free to enhance performance and reduce material consumption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If adhesive is applied to bond the membrane to plastic films during lamination, then bonding strength is improved, but active surface area is reduced due to coverage

Engineering Contradiction:
Improvebonding strengthVSAvoidactive surface area
Core Design Contradiction:
StrengthVSArea of stationary object

Solution Approach 1:

The adhesive application is transitioned from a two-dimensional surface coating (covering the membrane surface) to a one-dimensional edge application (coating only the peripheral edge). This dimensional reduction allows bonding functionality to be maintained while eliminating coverage of the active surface area, directly resolving the contradiction between bonding strength and active surface area preservation.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The adhesive coating is localized to specific regions (the peripheral edge) rather than being applied uniformly across the entire membrane surface. This local application strategy concentrates the bonding function where structurally necessary while preserving the quality and functionality of the active surface areas, thereby maintaining bonding strength without sacrificing active surface area.

Inventive Principle:
Principle #3Local quality

2Reliability

If adhesive is applied to ensure gas tightness, then gas barrier performance is improved, but active surface area is reduced

Engineering Contradiction:
Improvegas barrier performanceVSAvoidactive surface area
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

The gas barrier function is achieved by applying adhesive to the peripheral edge (one-dimensional approach) rather than coating the entire surface (two-dimensional approach). This edge-focused application creates an effective gas seal at the boundaries where gas crossover is most likely to occur, while preserving the active surface area for electrochemical reactions.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The adhesive is locally applied to the peripheral region where gas barrier functionality is most critical. This localized approach provides sufficient gas tightness at the edges without unnecessarily covering the active surface areas, thus improving gas barrier performance while minimizing loss of active surface area.

Inventive Principle:
Principle #3Local quality

3Stability of the object's composition

If adhesive is applied to bond membrane to plastic films, then structural integrity is improved, but manufacturing cost increases

Engineering Contradiction:
Improvestructural integrityVSAvoidmanufacturing cost
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The adhesive application process is simplified by reducing it to edge coating rather than full surface coating. This dimensional reduction decreases the quantity of adhesive required and simplifies the application process, thereby reducing manufacturing costs while still achieving the necessary structural integrity through proper edge bonding.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The adhesive is applied only where structurally necessary (at the edges), eliminating wasteful application to areas where bonding is not required. This local application strategy reduces material consumption and simplifies the manufacturing process, improving ease of manufacture and reducing costs while maintaining structural integrity.

Inventive Principle:
Principle #3Local quality

4Reliability

If adhesive is applied to create gas barrier, then gas separation is improved, but weight increases

Engineering Contradiction:
Improvegas separationVSAvoidfuel cell weight
Core Design Contradiction:
ReliabilityVSWeight of moving object

Solution Approach 1:

The gas barrier function is achieved through one-dimensional edge coating instead of two-dimensional surface coating. This reduces the total volume and mass of adhesive required, thereby reducing the overall weight of the fuel cell assembly while still providing effective gas separation at the critical boundary regions.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The adhesive is applied locally at the edges where gas separation is most critical, rather than uniformly across the entire surface. This localized approach minimizes the quantity of adhesive used, reducing material weight while maintaining sufficient gas separation performance at the interfaces where it is most needed.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach increases the performance of the fuel cell by maintaining active surfaces free from adhesive, reducing weight and manufacturing costs, and optimizing the gas barrier for efficient operation.

Implementation Method 1

The sealant and/or adhesive applied to the at least one end face of the coated membrane forms a gas barrier which serves to separate the reaction gases during operation of the subsequent fuel cell

Methodology Applied
Scientific EffectGas barrier:

Implementation Method 2

the sealant and/or adhesive creates a bond between the coated membrane and the plastic films of the gasket

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS20240372121A1Method for producing a membrane electrode assembly (MEA), membrane electrode assembly, and fuel cell comprising a membrane electrode assembly
Publication Date: 2024.11.07 ROBERT BOSCH GMBH
  • US20240372121A1 patent drawing
  • US20240372121A1 patent drawing
  • US20240372121A1 patent drawing

AI summary

The invention relates to a method for producing a membrane electrode assembly (10) for a fuel cell, wherein a membrane (1), preferably a polymer membrane, is coated on both sides with a catalytically active material in order to form a first and a second electrode (2, 3) and a sealant and/or adhesive (7) is applied to at least one end face (8) of the coated membrane (1), by means of which sealant or adhesive the coated membrane (1) is connected to two plastic films (5, 6) lying one on top of the other to form a gasket (4).The invention further relates to a membrane electrode assembly (10) and to a fuel cell comprising a membrane electrode assembly (10) according to the invention.