MEA Laminate Bonding with Production Aid for Continuous Handling

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Solution Overview

Problem

Existing methods for producing fuel cell membrane electrode units (MEAs) face challenges in handling and stability during large-scale production due to the time required for liquid adhesives to harden, leading to difficulties in handling and increased cycle times.

Innovation Solution

A method involving the use of a manufacturing aid applied to the composite of membrane and electrode materials before the adhesive hardens, providing immediate stability and allowing for continuous production processes like 'roll-to-roll' manufacturing, with options for UV-curable adhesives, pressure-sensitive adhesives, or hot melt adhesives that harden before the liquid adhesive, ensuring quicker stabilization and sealing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a liquid adhesive is used to join membrane and electrode components, then a gas-tight separation and bonding is achieved, but the uncured adhesive reduces handling stability and increases cycle time

Engineering Contradiction:
Improvegas-tight separationVSAvoidhandling stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

A manufacturing aid is applied to the membrane-electrode composite before the liquid adhesive has cured, providing preliminary stabilization. This allows the uncured composite to be handled with sufficient stability during production while the adhesive continues to cure and provide gas-tight sealing.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The manufacturing aid acts as an intermediary substance between the membrane-electrode composite and the external environment. It provides temporary handling stability without interfering with the adhesive's gas-tight sealing function, allowing decoupling of handling requirements from sealing requirements.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If a liquid adhesive is used to join membrane and electrode components, then a gas-tight separation and bonding is achieved, but the curing time increases production cycle time

Engineering Contradiction:
Improvegas-tight separationVSAvoidproduction cycle time
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The manufacturing aid provides preliminary stabilization immediately after adhesive application, allowing subsequent production steps to proceed without waiting for full adhesive curing. This overlaps the adhesive curing process with other production activities, reducing overall cycle time while maintaining gas-tight separation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The manufacturing aid enables continuous production flow by maintaining handling stability throughout the adhesive curing period. Production operations can continue uninterrupted rather than pausing for adhesive cure, thereby reducing production cycle time while the adhesive continues to provide gas-tight sealing.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables reliable handling and faster production of MEAs by providing immediate stability to the uncured composite, allowing for quicker processing and integration into fuel cell stacks without compromising the active area's functionality.

Implementation Method 1

applying a liquid adhesive to a surface of the membrane material and/or to a surface of the electrode material, and contacting the surfaces of the membrane material and the electrode material to form a material-to-material bond by means of the liquid adhesive

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

options for UV-curable adhesives, or hot melt adhesives that harden before the liquid adhesive

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentEP4150692B1Method for the manufacture of a membrane electrode assembly laminate containing at least 2 layers
Publication Date: 2024.01.24 AUDI AG
  • EP4150692B1 patent drawingFigure 1

AI summary

The invention relates to a method for producing an at least two-layer laminate of a membrane electrode assembly (MEA) for a fuel cell (1), comprising the steps: - providing a membrane material consisting of a proton-conducting electrolyte, - providing an electrode material which comprises at least one catalyst, - applying a liquid adhesive to a surface of the membrane material and/or to a surface of the electrode material, and - contacting the surfaces of the membrane material and of the electrode material in order to form an integrally bonded connection by means of the liquid adhesive, wherein a production aid is additionally introduced into or applied to a composite which is formed from the electrode material, from the membrane material and the as yet uncured liquid adhesive, wherein the production aid is configured to stabilize the uncured composite.