Microbial Electrolysis for GOSP Wastewater and Hydrogen Co-Production

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Solution Overview

Problem

Gas oil separation plants (GOSP) face challenges in efficiently treating oil and gas wastewater while producing clean energy, as existing methods are costly and environmentally impactful.

Innovation Solution

Integration of microbial electrolysis with hydrogen oxidation in a microbial electrolysis cell (MEC) to simultaneously treat oil and gas wastewater and produce hydrogen gas, which can be used to generate electrical power within the GOSP.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional wastewater treatment methods are used in GOSP, then wastewater treatment is achieved, but operational costs increase and environmental impact worsens

Engineering Contradiction:
Improvewastewater treatment effectivenessVSAvoidoperational costs
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent converts the harmful hydrocarbons in wastewater into beneficial hydrogen gas through microbial electrolysis. The hydrocarbons that would normally require expensive chemical treatment or incineration are instead used as substrate for hydrogen-producing bacteria, transforming a waste stream into a clean energy source while treating the wastewater

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The system uses the wastewater itself as the fuel source for hydrogen production. The hydrocarbons present in the wastewater serve as the substrate for microbial electrolysis, eliminating the need for external fuel sources or additional chemical reagents that would increase operational costs

Inventive Principle:
Principle #25Self-service

2Power

If microbial electrolysis is used to produce hydrogen, then clean energy is generated, but the device complexity increases

Engineering Contradiction:
Improvehydrogen productionVSAvoidsystem complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The microbial electrolysis cell serves multiple functions simultaneously: it treats wastewater by removing hydrocarbons, produces hydrogen gas as a clean energy carrier, and generates electrical current that can be used to power the system. This multi-functionality reduces the need for separate treatment systems and energy generation systems

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges the wastewater treatment process with the hydrogen production process into a single integrated system. The microbial electrolysis cell combines biological degradation of hydrocarbons with electrochemical hydrogen generation, eliminating the need for separate treatment and energy production facilities

Inventive Principle:
Principle #5Merging (Combining)

3Power

If hydrogen gas is produced and stored, then clean energy is available, but safety risks increase due to hydrogen flammability

Engineering Contradiction:
Improveclean energy availabilityVSAvoidhydrogen flammability
Core Design Contradiction:
PowerVSObject-affected harmful factors

Solution Approach 1:

The system maintains continuous production and immediate utilization of hydrogen gas. The hydrogen is generated continuously through microbial electrolysis and directly fed to the fuel cell for electricity generation, eliminating the need for hydrogen storage and transport operations that would create safety risks

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent introduces an on-site fuel cell as an intermediary device that converts hydrogen to electricity immediately at the point of production. This intermediary step allows the system to benefit from hydrogen's high energy density while avoiding the safety issues associated with storing and transporting large volumes of gaseous hydrogen

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces the oil content of wastewater, produces clean energy, and recycles treated wastewater for further use, reducing operational costs and environmental impact.

Implementation Method 1

The MEC electrolyzes the hydrocarbons to produce hydrogen ions at the anode side

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

The membrane allows the hydrogen ions and water molecules to pass through the membrane from the anode side to the cathode side

Methodology Applied
Scientific EffectOsmosis: Osmosis

Implementation Method 3

The MEC combines the hydrogen ions at the cathode side to produce hydrogen gas

Methodology Applied
Scientific EffectHydrogen evolution reaction:

Implementation Method 4

The hydrogen gas stream is oxidized into water. Electrical power is generated in response to oxidizing the hydrogen gas into water

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 5

The hydrogen gas stream is oxidized into water. Electrical power is generated in response to oxidizing the hydrogen gas into water

Methodology Applied
Scientific EffectFuel cell reaction: Fuel Cell

Data Source

PatentUS20250075343A1Crude oil processing plant wastewater treatment with co-production of hydrogen for clean energy
Publication Date: 2025.03.06 SAUDI ARABIAN OIL CO
  • US20250075343A1 patent drawing
  • US20250075343A1 patent drawing
  • US20250075343A1 patent drawing

AI summary

A wastewater stream is flowed from a separator to an anode side of a microbial electrolysis cell (MEC). The wastewater stream includes water and hydrocarbons. The separator is positioned in a gas-oil separation plant. The MEC electrolyzes the hydrocarbons to produce hydrogen ions. A membrane separates the MEC into the anode side and a cathode side. The membrane allows the hydrogen ions and water molecules to pass through the membrane from the anode side to the cathode side, thereby forming a treated wastewater stream at the cathode side. The MEC combines the hydrogen ions at the cathode side to produce hydrogen gas. The treated wastewater stream and a hydrogen gas stream is discharged from the cathode side. The hydrogen gas stream includes the hydrogen gas produced by the MEC. The hydrogen gas stream is oxidized into water. Electrical power is generated in response to oxidizing the hydrogen gas into water.