Mechanical Refining of Cellulose-Rich Solids for Sugar Extraction

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current methods for producing fermentable sugars from lignocellulosic biomass are limited in efficiently converting cellulose into sugars for ethanol and other fuel and chemical production, as they do not effectively address the extraction and conversion of cellulose-rich materials.

Innovation Solution

A process involving mechanical refining of cellulose-rich solids followed by enzymatic hydrolysis, combined with steam or hot-water treatment and optional acid catalysts, to release fermentable sugars from lignocellulosic biomass, allowing for the production of additional fermentation products like ethanol, n-butanol, and succinic acid.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If mechanical refining is applied to cellulose-rich solids, then the conversion of cellulose into fermentable sugars is enhanced, but the process complexity increases

Engineering Contradiction:
Improveconversion of cellulose into fermentable sugarsVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The process is divided into distinct sequential stages: mechanical refining stage, enzymatic hydrolysis stage, and fermentation stage. Each stage performs a specific function - mechanical refining breaks down cellulose structure, enzymatic hydrolysis converts cellulose to sugars, and fermentation produces biofuels. This segmentation allows optimization of each stage independently while maintaining overall process efficiency.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Mechanical refining is performed as a preliminary action before enzymatic hydrolysis. The mechanical refining pre-treats the cellulose-rich solids to break down the crystalline structure and increase surface area, making the subsequent enzymatic hydrolysis more efficient. This preliminary mechanical treatment prepares the substrate for better enzyme access and reaction.

Inventive Principle:
Principle #10Preliminary action

2Quantity of substance

If steam or hot-water treatment is used to extract hemicelluloses, then the yield of fermentable sugars is improved, but energy consumption increases

Engineering Contradiction:
Improveyield of fermentable sugarsVSAvoidenergy consumption
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

The steam or hot-water treatment operates at controlled temperature and pressure parameters to optimize hemicellulose extraction. By adjusting these parameters, the process achieves effective extraction of hemicelluloses while minimizing excessive energy consumption. The treatment conditions are optimized to balance extraction efficiency with energy usage.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The steam or hot-water treatment extracts hemicelluloses from the biomass matrix, separating them from cellulose and lignin. This extraction step removes the interfering hemicellulose component, allowing subsequent enzymatic processes to focus on cellulose conversion to fermentable sugars with higher efficiency.

Inventive Principle:
Principle #2Taking out (Extraction)

3Quantity of substance

If enzymatic hydrolysis is applied to cellulose-rich solids, then the production of cellulosic sugars is enhanced, but the process time increases

Engineering Contradiction:
Improveproduction of cellulosic sugarsVSAvoidprocess time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

Mechanical refining is performed as a preliminary action before enzymatic hydrolysis. The mechanical refining pre-treats the cellulose-rich solids to break down the crystalline structure and increase surface area, making the subsequent enzymatic hydrolysis more efficient. This preliminary mechanical treatment prepares the substrate for better enzyme access and reaction.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The enzymatic hydrolysis is conducted under optimized temperature, pH, and enzyme concentration parameters to maximize sugar production rate. By optimizing these parameters, the process achieves high cellulosic sugar production while minimizing the time required for hydrolysis.

Inventive Principle:
Principle #35Parameter changes

4Productivity

If multiple treatment steps are combined for biomass processing, then the efficiency of sugar extraction is improved, but the device complexity increases

Engineering Contradiction:
Improveefficiency of sugar extractionVSAvoiddevice complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The process is divided into distinct sequential stages: mechanical refining stage, enzymatic hydrolysis stage, and fermentation stage. Each stage performs a specific function - mechanical refining breaks down cellulose structure, enzymatic hydrolysis converts cellulose to sugars, and fermentation produces biofuels. This segmentation allows optimization of each stage independently while maintaining overall process efficiency.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Multiple treatment steps are combined in an integrated process flow where the output of one stage becomes the input for the next. The mechanical refining, enzymatic hydrolysis, and fermentation steps are merged into a coordinated sequence that maximizes sugar extraction efficiency while managing process complexity through systematic integration.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process enhances the conversion of cellulose into fermentable sugars, improving the yield of biofuels and chemicals by effectively breaking down cellulose-rich solids into usable monomers and oligomers, thereby increasing the efficiency of sugar extraction and fermentation.

Implementation Method 1

refining said initial mixture to mechanically release said monomeric sugar

Methodology Applied
Scientific EffectMechanical force: Mechanical Force

Implementation Method 2

fermenting said monomeric sugar with said sugar-fermenting microorganism to produce an initial quantity of a fermentation product

Methodology Applied
Scientific EffectFermentation: Fermentation

Implementation Method 3

digesting said intermediate mixture with a solution including steam and/or hot water in a digestor

Methodology Applied
Scientific EffectThermal digestion: Heating

Implementation Method 4

introducing said digested stream to an enzymatic hydrolysis unit under effective hydrolysis conditions to produce cellulosic sugars from said cellulose-rich solids

Methodology Applied
Scientific EffectEnzymatic hydrolysis: Hydrolysis

Implementation Method 5

fermenting said cellulosic sugars to produce an additional quantity of said fermentation product

Methodology Applied
Scientific EffectFermentation: Fermentation

Data Source

PatentEP3307897B1Hydrothermal-mechanical treatment of lignocellulosic biomass for production of fermentation products
Publication Date: 2022.01.26 VALMET AB
  • EP3307897B1 patent drawingFigure 1
  • EP3307897B1 patent drawingFigure 2
  • EP3307897B1 patent drawingFigure 3

AI summary

A simple process for converting lignocellulosic biomass into fermentation products is disclosed. Biomass may be subjected to a steam or hot-water soak to dissolve hemicelluloses. This step is followed by mechanical refining, such as in a hot-blow refiner, of the cellulose-rich (and lignin-rich) solids. The refined solids are then enzymatically hydrolyzed to generate sugars. Certain embodiments provide a process for producing ethanol, comprising: digesting a cellulosic biomass feedstock with steam or hot water to produce cellulose-rich solids, hemicellulose oligomers, and lignin; conveying the digested stream through a blow-line refiner; separating a vapor from the refined stream; introducing the refined stream to an enzymatic hydrolysis unit to produce sugars; fermenting the sugars to produce ethanol in dilute solution; and concentrating the dilute solution to produce an ethanol product. Enzymes and microorganisms may be introduced at various points in the process. The invention may be applied to any other fermentation product.