Melt Crystallization for Diisocyanate Isomer Separation

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Solution Overview

Problem

Existing methods for purifying diisocyanates, such as MDI, are capital and energy intensive due to the difficulty in separating isomers like 4,4' MDI from impurities like 2,4' and 2,2' MDI, often requiring multiple steps and high temperatures that lead to dimerization and reduced yields.

Innovation Solution

A suspension-based melt crystallization process that operates continuously, minimizing spontaneous nucleation and growing crystals in an undercooled melt with a large surface area for slow growth rates, followed by solid-liquid separation in a wash column with countercurrent washing, allowing for the production of pure and technical grade MDI streams without remelting or frequent process repetitions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If distillation or vacuum distillation is used to separate isomers, then separation of impurities is achieved, but capital and energy consumption increases

Engineering Contradiction:
Improveseparation purityVSAvoidenergy consumption
Core Design Contradiction:
Measurement precisionVSUse of energy by moving object

Solution Approach 1:

The patent employs freeze crystallization, a phase transition process where the MDI mixture is cooled below its freezing point to form crystals. The 4,4'-MDI crystallizes preferentially while impurities remain in the liquid phase, enabling separation without the high energy consumption of distillation. This is achieved by controlling temperature to exploit differences in freezing points and solubility of different MDI isomers.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The process changes physical parameters (temperature, concentration) to achieve separation. By gradually cooling the mixture and controlling the degree of supersaturation, the patent optimizes crystal formation and impurity rejection. The mother liquor is recycled and reprocessed, maximizing recovery while minimizing energy use compared to conventional distillation methods.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If high temperatures are used for separation, then separation efficiency improves, but dimerization increases and yields decrease

Engineering Contradiction:
Improveseparation efficiencyVSAvoiddimerization
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent uses freeze crystallization at temperatures below the freezing point of MDI (typically -10°C to 0°C), completely avoiding the high temperatures that cause dimerization. The phase transition from liquid to solid occurs at low temperatures where the isocyanate groups remain stable and do not undergo unwanted condensation reactions.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The patent replaces thermal separation (distillation requiring high temperatures) with a cryogenic crystallization process. This substitution of the separation mechanism allows efficient isomer separation based on solid-liquid equilibrium at low temperatures, eliminating the dimerization problem inherent in thermal processes.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If multiple separation steps are used, then purity increases, but process complexity and time increase

Engineering Contradiction:
Improveproduct purityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent achieves high purity (99.5-99.9% 4,4'-MDI) in a single freeze crystallization step by optimizing nucleation and crystal growth conditions. The preferential crystallization of 4,4'-MDI from the mixture, combined with controlled filtration and mother liquor removal, delivers pharmaceutical-grade purity without requiring multiple sequential separation operations.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The process includes preliminary steps of controlling supersaturation and nucleation to ensure selective crystal formation of 4,4'-MDI. By pre-conditioning the solution and controlling the crystallization kinetics, the patent ensures that impurities are excluded from the crystal lattice, achieving high purity in one operation rather than requiring multiple purification steps.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method efficiently produces high-purity MDI products with reduced dimerization and energy consumption, achieving high yields and stability, and can produce industrially relevant MDI mixtures in a single process step with adjustable product compositions.

Implementation Method 1

cooling said MDI feed stream below its freezing point to form 4,4' MDI crystals

Methodology Applied
Scientific EffectFreezing: Freezing

Implementation Method 2

cooling said slurry to form an under-cooled melt, by which said crystals further grow

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentEP2398767B1Process for crystallizing and separating different diisocyanate isomers
Publication Date: 2015.05.13 GEA NIRO PT
  • EP2398767B1 patent drawingFigure 1
  • EP2398767B1 patent drawingFigure 2
  • EP2398767B1 patent drawingFigure 3

AI summary

The invention relates to a method for separating an isocyanate mixture which contains at least two isomers of the respective isocyanate and various additional impurities simultaneously into two product streams which are characterized by different ratios of the two main isomers and where none of two products have a purity of main isomers greater 99 wt.% by means of a suspension-based melt crystallization process combined with a subsequent separation of the crystals in a wash column.