Melt-Processed Resin Article Surface Migration

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Solution Overview

Problem

Conventional resin articles face challenges in achieving excellent mechanical and surface characteristics due to degradation when exposed to environmental factors like oxygen, ozone, and light, necessitating additional coating or plating processes that increase manufacturing time and cost, while methods to improve scratch and heat resistance often compromise process efficiency and product strength.

Innovation Solution

A melting-processed resin article with a layer separation structure comprising a first resin layer, a second resin layer, and an interface layer, where the second resin layer is formed on the surface due to differences in surface energy, melt viscosity, or solubility parameters, eliminating the need for additional coating or plating and enhancing mechanical and surface characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If coating or plating process is applied to improve surface characteristics and weather resistance, then scratch resistance and heat resistance are improved, but manufacturing time increases and productivity decreases

Engineering Contradiction:
Improvesurface characteristicVSAvoidmanufacturing efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The resin composition is segmented into multiple functional components: a base resin providing structural integrity, and a surface-modifying resin containing polar groups that migrates to the surface during molding to provide scratch and heat resistance. This eliminates the need for separate coating processes while maintaining high productivity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The surface-modifying resin is pre-mixed into the base resin composition before molding. During the molding process, the polar groups automatically migrate to the surface through thermal and concentration gradients, preparing the surface with protective characteristics before the product even leaves the mold, thus eliminating subsequent coating steps.

Inventive Principle:
Principle #10Preliminary action

2Strength

If inorganic particles are added to improve wear resistance and hardness, then physical properties are improved, but processability and impact strength deteriorate

Engineering Contradiction:
Improvewear resistanceVSAvoidprocessability
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

Instead of changing the physical form of the resin by adding inorganic particles, the invention changes the chemical composition parameters by incorporating a surface-modifying resin with polar groups. This modifies the surface properties through molecular-level interactions rather than physical reinforcement, maintaining excellent processability while achieving the desired wear and heat resistance.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If additional resin with excellent scratch resistance is added to improve surface characteristic, then scratch resistance is improved, but additional curing process is needed and physical properties may not be improved to the required extent

Engineering Contradiction:
Improvescratch resistanceVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention merges the base resin and surface-modifying resin into a single homogeneous composition that is processed in one injection molding step. The surface modification occurs automatically during the molding process through migration of polar groups, combining surface treatment and structural forming into a single operation without requiring separate curing or coating processes.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resin article achieves improved mechanical and surface characteristics without additional coating or plating, reducing manufacturing time and cost, and increasing productivity by utilizing a blend of specific resins that separate during the melting process, forming a novel structure with the second resin layer exposed to ambient air.

Implementation Method 1

the layer separation structure is obtained by a layer separation caused by a difference in surface energy, melt viscosity or solubility parameters between the first resin and the second resin

Methodology Applied
Scientific EffectSurface energy difference: Surface Tension

Implementation Method 2

a layer separation structure, comprising: a first resin layer comprising a first resin; a second resin layer comprising a second resin formed on the first resin layer, and an interface layer including the first resin and the second resin and formed between the first resin layer and the second resin layer

Methodology Applied
Scientific EffectPhase separation:

Data Source

PatentEP2578393B1Melt-processed molded resin article
Publication Date: 2019.07.24 LG CHEM LTD
  • EP2578393B1 patent drawingFigure 1~2C
  • EP2578393B1 patent drawingFigure 3
  • EP2578393B1 patent drawing

AI summary

Provided is a melting-processed resin article including a first resin layer and a second resin layer formed on the first resin layer. Also, the component of the first resin layer is detected on a surface of the second resin layer by infrared spectrometer. Thus, the melting-processed resin article may have excellent mechanical and surface characteristics without application of an additional coating process, and exhibit an effect such as reduction of a manufacturing time and/or cost, and an increase in productivity.