Meltable Acrylate Adhesive Layers for Resealable Packaging

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Solution Overview

Problem

Existing pressure-sensitive adhesives for resealable packaging often fail to meet requirements for strong adhesive effect after repeated use, are prone to high opening forces, and can emit odors, necessitating additional barrier layers that increase production costs and complexity.

Innovation Solution

Acrylate polymers with specific monomer compositions and photoinitiators are used to create odor-free pressure-sensitive adhesive layers that maintain adhesive strength and resealability without the need for barrier layers, ensuring reliable closure and low odor emissions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional pressure-sensitive adhesives (e.g., styrene-butadiene block copolymers) are used, then adhesive strength is achieved, but barrier layers are required to prevent migration of plasticizers and tackifiers, increasing production costs and complexity

Engineering Contradiction:
Improveadhesive strengthVSAvoidproduction complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the harmful components (plasticizers and tackifiers) from the adhesive system by using a photopolymerizable adhesive composition based on acrylate or vinyl silane monomers that cures to form a crosslinked network, thereby preventing migration without requiring barrier layers

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical composition and curing mechanism of the adhesive from conventional non-crosslinked block copolymers to photopolymerizable acrylate or vinyl silane systems that form crosslinked structures upon UV irradiation, fundamentally altering the adhesive's molecular structure to prevent component migration

Inventive Principle:
Principle #35Parameter changes

2Strength

If conventional pressure-sensitive adhesives are used, then initial adhesion is achieved, but adhesive effect decreases significantly after repeated opening and closing

Engineering Contradiction:
Improveadhesive effectVSAvoiddurability after repeated use
Core Design Contradiction:
StrengthVSDuration of action of stationary object

Solution Approach 1:

The invention applies preliminary action by curing the adhesive composition with UV irradiation before the packaging is put into service, pre-forming the crosslinked network structure that provides durable adhesive performance from the first use and maintains it through repeated opening and closing cycles

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention uses a composite adhesive system combining photopolymerizable monomers (acrylate or vinyl silane) with specific functional additives, creating a crosslinked composite material that exhibits superior durability and resistance to degradation compared to conventional linear polymer adhesives

Inventive Principle:
Principle #40Composite materials

3Strength

If pressure-sensitive adhesives containing vinyl acetate or block copolymers are used, then adhesive properties are achieved, but odor emissions occur

Engineering Contradiction:
Improveadhesive propertiesVSAvoidodor emissions
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The invention converts the potential harm of using simple monomer systems (which might lack sufficient adhesion) into a benefit by incorporating photopolymerizable acrylate or vinyl silane monomers that, when crosslinked, provide both strong adhesive properties and complete freedom from odor, eliminating the need for vinyl acetate or block copolymers that generate odors

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Object-affected harmful factors

If barrier layers are added to prevent adhesive component migration, then safety is improved, but production effort and costs increase

Engineering Contradiction:
Improvecomponent migration preventionVSAvoidproduction effort
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The invention extracts and eliminates the need for barrier layers by designing an adhesive composition based on photopolymerizable acrylate or vinyl silane monomers that cures to a crosslinked structure, inherently preventing migration of components without requiring additional barrier layers

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention merges the adhesive function with the safety function by creating a single-phase photopolymerizable adhesive composition that simultaneously provides adhesion and prevents component migration through its crosslinked structure, eliminating the need for separate barrier layers

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The acrylate polymer-based adhesive layers provide consistent resealability and low odor, maintaining adhesive strength after multiple openings and closures, and do not require additional barrier layers, thus simplifying production and reducing costs.

Implementation Method 1

acrylate polymers with a glass transition temperature below -20 °C, determined according to ASTM-D 3418/82, which contain 1 to 30 mmol of polymerized photoinitiator per kg of acrylate polymer

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Implementation Method 2

acrylate polymers with a glass transition temperature below -20 °C

Methodology Applied
Scientific EffectGlass transition:

Data Source

PatentEP2265440B1Use of meltable acrylate polymers for producing contact adhesive layers
Publication Date: 2012.01.25 BASF SE
  • EP2265440B1 patent drawing

AI summary

The present invention relates to the use of meltable acrylate polymers for producing contact adhesive layers in resealable packagings. Moreover, the invention relates to multiple-layer films which have a contact adhesive layer on the basis of meltable acrylate polymers, to a method for producing said multiple-layer films, and to the use of said multiple-layer films for producing resealable packagings.