Membrane Coalescing Contactor for Polymer-Flood Produced Water

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Solution Overview

Problem

Current methods for treating polymer-flood produced water are inefficient and costly due to high viscosity issues, leading to chemical loss and revenue loss, as conventional methods fail to effectively separate oil and viscosifying polymers, and existing processes like oxidizing agents result in excessive consumption and inability to recover oil.

Innovation Solution

A method utilizing a membrane coalescing contactor to separate pure oil streams and deoiled viscosified water containing residual viscosifying polymers, where the membrane coalescing contactor employs microporous hollow fiber or tubular membranes to coalesce oil droplets and separate them from the water phase, allowing for the recovery of both oil and polymers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional treatment methods (flotation, gravity separation, liquid/liquid hydrocyclones) are used on polymer-flood produced water, then the treatment process is simple, but the methods are ineffective due to high viscosity

Engineering Contradiction:
Improvetreatment effectivenessVSAvoidtreatment process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs a membrane coalescing contactor with microporous hollow fiber membranes to separate oil and polymer from produced water. The porous membrane structure allows water to pass through while retaining oil droplets and polymer molecules, effectively addressing the high viscosity problem that renders conventional separation methods ineffective.

Inventive Principle:
Principle #31Porous materials

2Speed

If oxidizing agents are used to break polymer chains and reduce viscosity, then the produced water viscosity is reduced below 2 cps in less than 5 hours, but this induces chemical loss and high oxidizing agent consumption costs

Engineering Contradiction:
Improveviscosity reduction speedVSAvoidpolymer loss
Core Design Contradiction:
SpeedVSLoss of substance

Solution Approach 1:

The patent extracts and removes polymers from the produced water stream using membrane coalescence technology, allowing polymer recovery and reuse. This eliminates the need for oxidizing agents that break down polymer chains, preventing chemical loss and avoiding the costs associated with excessive oxidizing agent consumption.

Inventive Principle:
Principle #2Taking out (Extraction)

3Speed

If oxidizing agents are used to treat produced water, then viscosity is reduced quickly, but oil cannot be recovered which induces revenue loss

Engineering Contradiction:
Improvetreatment speedVSAvoidrevenue loss
Core Design Contradiction:
SpeedVSLoss of energy

Solution Approach 1:

The patent segments the separation process into distinct phases using the membrane coalescing contactor: oil droplets are coalesced and separated from the water phase, while polymer molecules are retained and recovered. This segmentation allows simultaneous recovery of both oil and polymer without requiring oxidizing agents, preventing revenue loss while maintaining treatment effectiveness.

Inventive Principle:
Principle #1Segmentation

4Productivity

If produced water is reinjected to reduce environmental footprint and water management costs, then environmental and operational benefits are achieved, but reservoir plugging occurs due to undesired compounds

Engineering Contradiction:
Improvewater management efficiencyVSAvoidreservoir plugging risk
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the composition parameters of produced water by removing oil and polymer contaminants through membrane coalescence treatment. This parameter modification eliminates harmful substances that could cause reservoir plugging, enabling safe reinjection while maintaining the environmental and operational benefits of water reuse.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively separates oil and viscosifying polymers, reducing chemical and operational costs by enabling efficient oil recovery and polymer reuse, while allowing deoiled water to be reinjected or discharged, thus improving the economic viability of water management in oil and gas fields.

Implementation Method 1

a first step of directing the produced water to a membrane coalescing contactor

Methodology Applied
Scientific EffectCoalescence: Coagulation

Implementation Method 2

recovering : ∘ the pure oil stream from the membrane of said membrane coalescing contactor

Methodology Applied
Scientific EffectMembrane filtration: Semipermeable Membrane

Data Source

PatentEP3181655B1Method for recovering oil and viscosifying polymers in polymer-flood produced water
Publication Date: 2020.02.05 SUEZ GRP SAS
  • EP3181655B1 patent drawingFigure 1
  • EP3181655B1 patent drawingFigure 2A~2B

AI summary

The present invention concerns a method for recovering pure oil stream and viscosifying polymers in polymer-flood produced water issued from an oil and gas field using a membrane coalescing contactor.