Fuel Cell Membrane Electrode Assembly Gas Diffusion

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Solution Overview

Problem

Fuel cells face challenges in achieving high power generation performance due to insufficient adhesion between the gas diffusion layer and the catalyst layer, as well as inadequate water removal, which leads to blocked gas diffusion paths and reduced reaction efficiency.

Innovation Solution

A membrane-electrode assembly is designed with a pair of catalyst layers and gas diffusion layers, where the gas diffusion layers contain a higher mass percentage of fibrous conductive members compared to the catalyst layers, enhancing gas diffusivity and water removal efficiency by ensuring the fibrous conductive members in both layers have similar physical properties and structures, thereby preventing water from blocking gas diffusion paths.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If the gas diffusion layer contains fluorocarbon resin, boron-modified carbon, and fibrous carbon with fibrous carbon at 5 to 50 parts by weight per 100 parts by mass of boron-modified carbon, then the structural stability is maintained, but the adhesion with the catalyst layer and water removal are insufficient

Engineering Contradiction:
Improvestructural stabilityVSAvoidadhesion and water removal
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent changes the key parameter of fibrous carbon content in the gas diffusion layer from the conventional 5-50 parts by weight per 100 parts by mass of boron-modified carbon to 100-300 parts by weight per 100 parts by mass of boron-modified carbon. This parameter change transforms the gas diffusion layer's properties to achieve both excellent adhesion with the catalyst layer and superior water removal capability, while maintaining structural stability through the optimized carbon material composition including fluorocarbon resin and boron-modified carbon

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If the gas diffusion layer uses conventional carbon materials, then the manufacturing simplicity is maintained, but the power generation performance is insufficient due to poor adhesion and water removal

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidpower generation performance
Core Design Contradiction:
Ease of manufactureVSPower

Solution Approach 1:

The patent employs a composite material system in the gas diffusion layer comprising fluorocarbon resin, boron-modified carbon, and fibrous carbon in a specific ratio (100-300:100:5-50 parts by weight). This composite structure combines the water-repellent properties of fluorocarbon resin, the structural stability of boron-modified carbon, and the high surface area and conductivity of fibrous carbon, achieving excellent adhesion and water removal while maintaining manufacturing simplicity through a straightforward mixing and pressing process

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration improves the power generation performance of fuel cells by enhancing gas diffusivity and water removal, reducing the likelihood of flooding and maintaining efficient gas diffusion, leading to improved reaction efficiency and overall performance.

Implementation Method 1

enhancing gas diffusivity

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

enhancing water removal

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Data Source

PatentUS20220149409A1Membrane electrode assembly and fuel cell
Publication Date: 2022.05.12 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US20220149409A1 patent drawing
  • US20220149409A1 patent drawing

AI summary

A membrane-electrode assembly includes an electrolyte membrane, a pair of catalyst layers stacked on surfaces of the electrolyte membrane, and a pair of gas diffusion layers stacked on a side opposite to the electrolyte membrane of one of the pair of catalyst layers and on a side opposite to the electrolyte membrane of the other one of the catalyst layers. One of the pair of catalyst layers contains catalyst particles and a first conductive material. One of the pair of gas diffusion layers in contact with the one of the catalyst layers contains a second conductive material. The first conductive material includes a first particulate conductive member and a first fibrous conductive member, and the second conductive material includes a second fibrous conductive member. The content K2 by mass of the second fibrous conductive member is larger than the content K1 by mass of the first fibrous conductive member.