Membrane Electrode Assembly Asymmetric Layer Thickness

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Solution Overview

Problem

Conventional membrane electrode assemblies face challenges in enhancing thermal insulation on the cathode side and accelerating water transfer from the cathode to the anode, especially in high-temperature low-humid conditions, where the anode tends to dry out due to inefficient water transfer.

Innovation Solution

A membrane electrode assembly is designed with specific thickness relationships between the anode and cathode catalyst layers and gas diffusion layers, where T1+T3 < T2+T4, T1 < T2, and T3 > T4, utilizing carbon as a major factor for thermal insulation, ensuring greater thermal insulation on the cathode side and enhanced water transfer by maintaining equal thermal insulation performance per thickness across layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If the thickness relationship T1+T3≥T2+T4 is maintained, then thermal insulation on the anode side is enhanced, but thermal insulation on the cathode side cannot be sufficiently enhanced

Engineering Contradiction:
Improvecathode temperatureVSAvoidthickness relationship constraint
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The patent applies asymmetry by establishing different thickness relationships for the anode and cathode sides. Specifically, it sets T2+T4>T1+T3, creating an asymmetric structure where the cathode side (T2+T4) has greater total thickness than the anode side (T1+T3). This asymmetric design enables enhanced thermal insulation on the cathode side while maintaining functional balance in the fuel cell assembly.

Inventive Principle:
Principle #4Asymmetry

2Productivity

If thermal insulation on the cathode side is enhanced, then water transfer from cathode to anode is accelerated, but anode drying in high-temperature low-humid conditions occurs

Engineering Contradiction:
Improvewater transfer rateVSAvoidanode humidity stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies local quality by creating different thermal insulation characteristics in different regions of the membrane electrode assembly. The cathode side is designed with greater thermal insulation (T2+T4>T1+T3) to accelerate water transfer, while the anode side maintains相对较低的 insulation to prevent drying. This localized differentiation of thermal properties enables simultaneous optimization of water transfer efficiency and anode humidity stability.

Inventive Principle:
Principle #3Local quality

3Temperature

If T2+T4>T1+T3 is implemented, then thermal insulation on the cathode side is enhanced, but conventional configurations cannot accelerate water transfer

Engineering Contradiction:
Improvecathode temperatureVSAvoidwater transfer rate
Core Design Contradiction:
TemperatureVSProductivity

Solution Approach 1:

The patent applies parameter changes by modifying the thickness parameters T1, T2, T3, and T4 to establish the relationship T2+T4>T1+T3. This parameter adjustment changes the thermal insulation characteristics of the cathode side, creating a temperature differential that drives water vapor from the cathode to the anode. The specific parameter relationship enables both enhanced thermal insulation and accelerated water transfer simultaneously.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration effectively enhances thermal insulation on the cathode side, accelerating water transfer from the cathode to the anode, improving the overall performance of the fuel cell battery by maintaining higher cathode temperature and partial water vapor pressure, thereby facilitating efficient water diffusion.

Implementation Method 1

The anode catalyst layer, the cathode catalyst layer, the anode gas diffusion layer, and the cathode gas diffusion layer have the same thermal insulation performance per thickness. The membrane electrode assembly satisfies all relations of T1+T3<T2+T4

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 2

it is possible to accelerate the transfer of the water from the cathode to the anode

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 3

maintaining higher cathode temperature and partial water vapor pressure, thereby facilitating efficient water diffusion

Methodology Applied
Scientific EffectVapor pressure gradient: Vapour Pressure

Data Source

PatentUS9634346B2Membrane electrode assembly and fuel cell battery
Publication Date: 2017.04.25 TOYOTA JIDOSHA KK
  • US9634346B2 patent drawing
  • US9634346B2 patent drawing
  • US9634346B2 patent drawing

AI summary

A membrane electrode assembly for use in a fuel cell battery includes: an electrolyte membrane; an anode catalyst layer formed on a first surface of the electrolyte membrane; a cathode catalyst layer formed on a second surface of the electrolyte membrane; an anode gas diffusion layer stacked on the anode catalyst layer; and a cathode gas diffusion layer stacked on the cathode catalyst layer. The anode catalyst layer, the cathode catalyst layer, the anode gas diffusion layer, and the cathode gas diffusion layer have the same thermal insulation performance per thickness. The membrane electrode assembly satisfies all relations of T1+T3&lt;T2+T4, T1&lt;T2, and T3&gt;T4 where thicknesses of the anode catalyst layer, the cathode catalyst layer, the anode gas diffusion layer, and the cathode gas diffusion layer in a stacking direction are defined as T1, T2, T3, and T4, respectively.