Photoreactive 3D Printing Membrane Materials for Adhesion Reduction

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Solution Overview

Problem

Conventional photoreactive 3D printing systems face challenges with membrane materials that lack sufficient transparency, mechanical strength, and durability, leading to issues with adhesion and hydrostatic forces during printing, and are often costly to produce.

Innovation Solution

Development of membranes comprising polymeric blends with specific polymer combinations and additives that enhance transparency, mechanical properties, and oxygen permeability, allowing for the creation of an inhibition zone to reduce adhesion and hydrostatic forces, while being more cost-effective to manufacture.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If TEFLON® AF2400 membrane is used to achieve high oxygen permeability and reduce adhesion, then the photopolymerization inhibition zone is improved, but the mechanical strength and durability are insufficient

Engineering Contradiction:
Improveadhesion reductionVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent employs composite membrane structures combining TEFLON® AF2400 with other polymers or materials to achieve both high oxygen permeability and enhanced mechanical strength. The composite approach allows the membrane to maintain the inhibition zone benefit while gaining structural durability through material synergies.

Inventive Principle:
Principle #40Composite materials

2Reliability

If TEFLON® AF2400 membrane is used to create inhibition zone, then adhesion between printed layer and membrane is reduced, but the transparency and manufacturing cost are compromised

Engineering Contradiction:
Improveadhesion reductionVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent explores using cost-effective alternative materials or coatings that can achieve similar inhibition zone effects without the high cost of TEFLON® AF2400. This may involve using disposable or easily replaceable membrane components that provide the necessary oxygen permeability at lower manufacturing costs.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Force

If membrane with high oxygen permeability is used to reduce hydrostatic forces, then the part release is improved, but the optical clarity and printing resolution are affected

Engineering Contradiction:
Improvehydrostatic force reductionVSAvoidprinting resolution
Core Design Contradiction:
ForceVSManufacturing precision

Solution Approach 1:

The patent implements local quality optimization by creating spatially varying membrane properties - regions with different oxygen permeability, thickness, or material composition. This allows the membrane to provide hydrostatic force reduction in specific areas while maintaining optical clarity in regions critical for printing resolution, achieving both functions simultaneously through localized property differentiation.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The new membrane materials provide high tensile strength, optical clarity, and durability, enabling faster printing rates, higher resolution, and reduced operating costs by minimizing adhesion and hydrostatic stress, while maintaining the performance of conventional membranes like TEFLON® AF2400 at lower production costs.

Implementation Method 1

The high oxygen permeability of TEFLON® AF2400 contributes to its unusually high oxygen permeability. The high oxygen permeability is advantageous because oxygen passing through the membrane creates an 'inhibition zone' in the resin pool adjacent to the membrane.

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 2

One method utilizes photoreactive resin (i.e., photopolymer) that cross-links and hardens from a liquid resin to a solid polymeric material upon exposure to light.

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS10844211B2Membrane materials for photoreactive additive manufacturing
Publication Date: 2020.11.24 INTREPID AUTOMATION INC
  • US10844211B2 patent drawing
  • US10844211B2 patent drawing
  • US10844211B2 patent drawing

AI summary

A photoreactive additive manufacturing system comprises a resin tub, a membrane, and a resin pool confined by the resin tub and the membrane. In some embodiments, the membrane comprises a polymeric blend comprising a first polymer and a second polymer, and the first polymer is a fluoropolymer. In some embodiments, the membrane comprises a polymer and an additive to control the free volume of the polymer.