Semipermeable Membrane Rejection Performance via Pressure Fluctuation

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing semipermeable membranes used in seawater desalination and wastewater recycling face challenges in maintaining rejection performance due to fouling and oxidative deterioration, leading to reduced water quality and increased treatment costs, with existing recovery methods being inefficient and difficult to control in real-world operations.

Innovation Solution

A method involving the use of a liquid containing a rejection performance enhancer, such as polyethylene glycol, which is pressurized and fed to the semipermeable membrane to enhance rejection performance by altering pressure and permeation flow rate, while maintaining the changed conditions for a specific duration to improve membrane efficiency without significantly reducing water permeation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a semipermeable membrane is used for seawater desalination or wastewater recycling, then water containing solutes can be purified, but the membrane suffers from fouling and oxidative deterioration leading to reduced rejection performance

Engineering Contradiction:
Improverejection performanceVSAvoidfouling and oxidative deterioration
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses polyethylene glycol as an intermediary substance that temporarily interacts with the membrane surface to restore rejection performance. The polyethylene glycol solution is circulated through the membrane, allowing the polymer to adsorb onto the membrane surface and restore its charge characteristics, thereby improving rejection of neutral molecules without permanently modifying the membrane structure

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical environment by introducing polyethylene glycol solution at specific concentrations (0.1-10% by weight) and circulation conditions (flow rate, temperature, pH control). These parameter changes create optimal conditions for the polyethylene glycol to interact with the membrane surface and restore its performance without causing damage

Inventive Principle:
Principle #35Parameter changes

2Reliability

If existing rejection performance recovery methods are used, then some performance improvement may be achieved, but the methods are inefficient and difficult to control in real-world operations

Engineering Contradiction:
Improverejection performanceVSAvoidoperational control
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent implements a feedback control system where rejection performance is monitored (through permeate analysis or flux measurement) and the polyethylene glycol treatment is adjusted accordingly. The circulation conditions, concentration, and duration of treatment are controlled based on measured performance parameters, enabling precise and efficient restoration of membrane performance

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system is designed to allow the membrane to partially restore its own performance through controlled exposure to polyethylene glycol solution under specific circulation conditions. The method enables the membrane treatment process to be self-regulating within defined operational parameters, reducing the need for complex external control mechanisms

Inventive Principle:
Principle #25Self-service

3Productivity

If pressure is increased to maintain water production, then permeate output is maintained, but rejection performance deteriorates further

Engineering Contradiction:
Improvewater productionVSAvoidrejection performance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies polyethylene glycol treatment before operating the membrane at high pressure to restore rejection performance in advance. By pre-treating the membrane with polyethylene glycol solution under controlled circulation conditions, the membrane's rejection characteristics are improved before subjected to high-pressure operation, preventing performance deterioration during production

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively enhances rejection performance for nonionic substances, improving water quality by minimizing permeation performance reduction and extending the life of semipermeable membranes, thereby reducing operational costs and maintaining consistent water production.

Implementation Method 1

a liquid containing a rejection performance enhancer, such as polyethylene glycol, which is pressurized and fed to the semipermeable membrane to enhance rejection performance by altering pressure and permeation flow rate

Methodology Applied
Scientific EffectPressure gradient: Pressure Gradient

Implementation Method 2

passing water containing a solute, such as salt, through a semipermeable membrane at a pressure not less than the osmotic pressure

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 3

The reverse osmosis method applied to seawater desalination or recycling of sewage or wastewater can produce desalinated water by passing water containing a solute, such as salt, through a semipermeable membrane at a pressure not less than the osmotic pressure

Methodology Applied
Scientific EffectReverse osmosis: Reverse Osmosis

Implementation Method 4

passing water containing a solute, such as salt, through a semipermeable membrane at a pressure not less than the osmotic pressure

Methodology Applied
Scientific EffectOsmotic pressure: Osmotic Pressure

Data Source

PatentEP3243562B1Method for improving inhibition performance of semipermeable membrane
Publication Date: 2022.01.05 TORAY INDUSTRIES INC
  • EP3243562B1 patent drawingFigure 1
  • EP3243562B1 patent drawingFigure 2
  • EP3243562B1 patent drawingFigure 3

AI summary

Disclosed is a method of enhancing a rejection performance of a semipermeable membrane by pressurizing and feeding a liquid containing a rejection performance enhancer to a primary side of the semipermeable membrane to come into contact with a membrane surface thereof, the method including: a step of changing, at least once during the feeding, a pressure or an osmotic pressure of the liquid containing the rejection performance enhancer at a fluctuation rate of 0.05 MPa/s or more, or a feed flow rate to the semipermeable membrane, thereby changing at least either a pressure acting on the membrane surface or a permeation flow rate from that at the time of normal treatment, followed by maintaining.