Membrane Gas-Liquid Separator for Fuel Cell Anode Recirculation
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Solution Overview
Problem
Existing gas-liquid separators in fuel cell systems are inefficient in separating liquid components like water and gaseous components like nitrogen from the exhaust gas, leading to reduced fuel cell efficiency and potential damage to system components.
Innovation Solution
A gas-liquid separator with a membrane that separates the interior space from the flow region, allowing only hydrogen to pass through while keeping water and nitrogen out, thereby improving the efficiency of the fuel cell system by reducing the recirculation of impurities.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If a conventional gas-liquid separator is used to separate water from exhaust gas, then liquid water can be removed, but gaseous components like nitrogen and impurities are not separated and are recirculated back into the fuel cell, reducing efficiency and potentially damaging components
Solution Approach 1:
The separator is divided into distinct functional zones: a first separation section for liquid-gas separation and a second separation section for gas-gas separation. This segmentation allows each section to specialize in removing specific components (water in the first section, nitrogen and impurities in the second section), thereby improving fuel cell efficiency without requiring a single overly complex separation system.
Solution Approach 2:
A hydrophobic membrane is introduced as an intermediary element between the exhaust gas stream and the separation zones. The membrane selectively permits hydrogen to pass through while blocking nitrogen and other impurities, enabling efficient gas-gas separation without complex mechanical systems. This intermediary membrane resolves the contradiction by providing selective separation through material properties rather than mechanical complexity.
2Productivity
If only liquid water separation is performed, then the separation system remains simple, but a large portion of gaseous water and nitrogen is recirculated back into the anode circuit, reducing fuel cell efficiency
Solution Approach 1:
The separator employs a two-stage segmentation approach: the first separation section removes liquid water through gravity and condensation, while the second separation section removes gaseous nitrogen and impurities through the hydrophobic membrane. This segmented architecture enables comprehensive separation of both liquid and gaseous components, improving productivity by ensuring high-purity hydrogen recirculation without requiring an overly complex single-stage system.
Solution Approach 2:
A hydrophobic porous membrane is utilized in the second separation section to achieve gas-gas separation. The membrane's porous structure with hydrophobic properties allows it to selectively transmit hydrogen molecules while blocking larger nitrogen molecules and impurities. This application of porous materials enables efficient removal of gaseous components, improving fuel cell productivity without significantly increasing device complexity.
3Reliability
If a membrane is introduced to separate hydrogen from other gases, then the proportion of hydrogen in recirculated gas increases, but the device complexity and manufacturing difficulty increase
Solution Approach 1:
The patent employs a hydrophobic porous membrane with specific pore size and surface properties to achieve selective gas separation. The membrane's porous structure is engineered to allow hydrogen molecules to pass through while blocking nitrogen and impurities based on molecular size and hydrophobicity. This use of porous materials provides an effective solution for component protection, and the membrane technology, while requiring precision manufacturing, leverages established materials science approaches to manage manufacturing complexity.
Solution Approach 2:
The hydrophobic membrane's selective permeability is achieved through specific parameter control: pore size, surface energy, and hydrophobicity. By optimizing these parameters, the membrane achieves high selectivity for hydrogen over nitrogen and impurities. This parameter-based approach allows for controlled manufacturing processes and quality control, balancing the need for reliable component protection with manufacturing feasibility.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The proposed solution effectively increases the proportion of hydrogen in the recirculated gas, enhancing the efficiency of the fuel cell system, reducing operating costs, and minimizing the risk of component damage from impurities.
Implementation Method 1
a separation of a component of the gaseous medium from the H2 takes place by means of the membrane
Implementation Method 2
the membrane is designed as a semipermeable membrane, wherein the membrane is permeable to the H2 component of the medium and wherein the membrane is impermeable to at least the H2O component of the medium
Implementation Method 3
the gaseous medium in the anode circuit causes a pressure difference between the flow region and the interior when flowing through the intake region
Data Source
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AI summary
The invention relates to a gas-liquid separator (2) in an anode circuit (25) of a fuel cell (30) for separating at least one liquid component, in particular H2O, from a gaseous component, in particular H2, having at least one container (6) to which a medium is supplied at least indirectly via a connection line (4) from an anode region (31) of the fuel cell (30) and/or a medium, in particular a propellant, is supplied via a dosing valve (8) by means of a tank line (21) from a tank (27), wherein a separation of at least the liquid component of the medium occurs in the container (6), the separated component of the medium being discharged from the container (6) via a return line (19), and the remaining gaseous component liquid of the medium, in particular H2, being fed back to the anode region (31) via an outflow line (5). According to the invention, the container (6) has an interior chamber (12) and a flow region (13), which are separated from each other by a membrane (34), wherein the flow region (13) is fluidically connected to the connection line (4) or to the tank line (21) and the outflow line (5), the interior chamber (12) being fluidically connected to the connection line (4), at least indirectly via a branch line (7), and the interior chamber (12) being fluidically connected, at least indirectly, to the return line (19), and wherein a component of the gaseous medium is separated from H2 by means of the membrane (34).