Separation Membrane Washing with Acidic Aromatic Solution

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Solution Overview

Problem

The clogging of separation membranes during the production of cellulose-derived sugar liquids leads to inefficiencies in impurity removal, as existing methods fail to effectively prevent membrane clogging over long-term operation.

Innovation Solution

A method involving washing the separation membranes with an aqueous solution containing both an aromatic compound and an acidic substance, specifically using compounds like hydroxymethylfurfural and acids such as sulfuric acid, to restore filtration rates and prevent membrane degradation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If separation membranes are used to remove impurities from cellulose-derived sugar liquid, then impurity removal efficiency is improved, but membrane clogging occurs during long-term operation

Engineering Contradiction:
Improveimpurity removal efficiencyVSAvoidmembrane clogging
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies preliminary action by performing membrane washing with an aqueous solution containing an aromatic compound and acidic substance before the membrane becomes severely clogged. This preventive maintenance approach restores membrane permeability and removes accumulated impurities, allowing continuous operation without frequent membrane replacement or severe clogging issues.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the chemical parameters of the washing solution by combining aromatic compounds (such as vanillin, ferulic acid, or coumaric acid) with acidic substances (such as oxalic acid, citric acid, or acetic acid). This specific combination of chemical parameters creates a synergistic effect that effectively removes both organic and inorganic impurities from the membrane surface, preventing clogging while maintaining filtration efficiency.

Inventive Principle:
Principle #35Parameter changes

2Duration of action of stationary object

If membrane washing is performed to prevent clogging, then membrane reuse is enabled, but additional washing steps are required

Engineering Contradiction:
Improvemembrane service lifeVSAvoidwashing process complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent applies universality by designing a washing solution that simultaneously addresses multiple types of membrane fouling - organic impurities, inorganic salts, and protein deposits - with a single aqueous solution containing both aromatic compound and acidic substance. This multi-functional washing approach simplifies the overall process by eliminating the need for multiple sequential washing steps with different chemicals.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent implements self-service by using a washing solution where the aromatic compound and acidic substance work synergistically to automatically remove various types of impurities without requiring complex multi-step procedures. The solution self-regulates to clean different types of fouling through the combined chemical actions, reducing the need for complex process control and multiple washing stages.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively prevents membrane clogging, allowing for the reuse of separation membranes and maintaining filtration efficiency, thereby enhancing the production process of cellulose-derived sugar liquids at a low cost.

Implementation Method 1

membrane washing with an aqueous solution containing both an aromatic compound and an acidic substance brings about a remarkable washing effect

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a method of separating fine particles into the feed side through filtration using a microfiltration membrane, a method of separating water-soluble macromolecules into the feed side through filtration using an ultrafiltration membrane, and a method of removing low-molecular weight compounds such as fermentation inhibitors from the filtrate side through a nanofiltration membrane or a reverse osmosis membrane

Methodology Applied
Scientific EffectFiltration: Filter (physical)

Data Source

PatentUS9863011B2Method of producing sugar solution
Publication Date: 2018.01.09 TORAY INDUSTRIES INC
  • US9863011B2 patent drawing
  • US9863011B2 patent drawing
  • US9863011B2 patent drawing

AI summary

A method of producing a sugar liquid includes filtering a cellulose-derived sugar liquid through one or more separation membranes selected from the group consisting of an ultrafiltration membrane, a nanofiltration membrane and a reverse osmosis membrane, and washing the separation membrane(s) after filtration with washing water containing an acidic substance and an aromatic compound.