Variable Resistance Memory Cell Structure for Switching Pattern Endurance

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Solution Overview

Problem

Existing variable resistance memory devices face challenges in maintaining the integrity of their switching patterns, leading to reduced endurance due to changes in composition during the manufacturing process.

Innovation Solution

The proposed solution involves a variable resistance memory device design with conductive lines that undergo a nitridation process before etching, incorporating a metal nitride upper pattern to prevent composition changes and enhance endurance. The device includes a specific structure with switching and variable resistance patterns, electrodes, and filler structures, ensuring the stability of the switching patterns.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional etching process is performed without nitridation, then the manufacturing process is simpler and faster, but the switching pattern composition changes leading to reduced endurance

Engineering Contradiction:
ImproveenduranceVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The nitridation process is performed as a preliminary treatment before the etching process. This preliminary action modifies the conductive line surface by forming a metal nitride layer, which then protects the switching pattern during subsequent etching operations, preventing composition changes and improving device endurance

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The metal nitride layer acts as an intermediary protective layer between the etching process and the switching pattern. This intermediate layer prevents direct contact between the etching chemistry and the switching pattern materials, thereby maintaining compositional integrity while enabling the etching process to proceed

Inventive Principle:
Principle #24Intermediary (Mediator)

2Stability of the object's composition

If nitridation process is added before etching, then switching pattern composition stability improves, but manufacturing time and process complexity increase

Engineering Contradiction:
Improveswitching pattern composition stabilityVSAvoidmanufacturing time
Core Design Contradiction:
Stability of the object's compositionVSLoss of time

Solution Approach 1:

The nitridation process is performed as a preliminary treatment before the etching process. This preliminary action modifies the conductive line surface by forming a metal nitride layer, which then protects the switching pattern during subsequent etching operations, preventing composition changes and improving device endurance

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The nitridation process changes the chemical composition and properties of the conductive line upper portion, transforming it into a metal nitride with different characteristics. This parameter change (chemical composition) creates a protective layer that stabilizes the switching pattern during etching, outweighing the time cost of the additional process step

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively inhibits changes in the composition of the switching patterns, thereby improving the endurance and stability of the variable resistance memory device by reducing contamination and maintaining the integrity of the switching patterns.

Implementation Method 1

The forming of the first conductive lines may include performing a nitridation process on upper portions of the first conductive lines

Methodology Applied
Scientific EffectNitridation: Nitriding

Data Source

PatentUS11856872B2Variable resistance memory device and method of manufacturing the same
Publication Date: 2023.12.26 SAMSUNG ELECTRONICS CO LTD
  • US11856872B2 patent drawing
  • US11856872B2 patent drawing
  • US11856872B2 patent drawing

AI summary

A variable resistance memory device includes first conductive lines extending in a first direction, second conductive lines extending in a second direction and crossing the first conductive lines in a plan view, and cell structures respectively provided at crossing points of the first conductive lines and the second conductive lines in the plan view. Each of the cell structures includes a switching pattern, a variable resistance pattern, and a first electrode provided between the switching pattern and the first conductive line, the first electrode including carbon. Each of the first conductive lines includes an upper pattern including a metal nitride in an upper portion thereof. The upper pattern is in contact with a bottom surface of the first electrode.