In-Sensor Span Calibration for MEMS Ozone Sensors

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Solution Overview

Problem

Miniature gas sensors, particularly metal oxide (MOX) sensors, face challenges with calibration drift due to chemical poisoning and deactivation, making them less suitable for mass market adoption in applications like environmental and health monitoring, as existing calibration techniques are not practical or economical, especially when generating and controlling target gases like ozone is difficult.

Innovation Solution

Incorporating a controllable UV light source within the gas-sensing device to generate ozone gas from ambient air, using short wavelength UV light or corona discharge, which allows for in-sensor span calibration by varying the intensity and duration of the UV source to create specific ozone concentrations, enabling effective calibration without the need for external reference equipment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If external reference equipment is used for calibration, then measurement precision is improved, but device complexity and cost increase significantly

Engineering Contradiction:
Improvecalibration accuracyVSAvoidcalibration system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent implements self-service calibration by integrating a UV light source directly into the sensor device, allowing it to generate its own calibration gas (ozone) without external reference equipment. The UV source photolytically decomposes oxygen to create ozone, enabling the sensor to calibrate itself autonomously

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent uses UV light as an intermediary substance to generate ozone in-situ. The UV light source acts as a mediator that converts ambient oxygen into calibration-grade ozone, eliminating the need for external ozone generators or reference instruments

Inventive Principle:
Principle #24Intermediary (Mediator)

2Measurement precision

If span calibration points are generated externally, then measurement precision is improved, but ease of operation deteriorates due to substantial generation and reference equipment requirements

Engineering Contradiction:
Improvespan calibration accuracyVSAvoidcalibration operation simplicity
Core Design Contradiction:
Measurement precisionVSEase of operation

Solution Approach 1:

The sensor device performs span calibration autonomously by generating its own calibration gas. The integrated UV light source creates ozone from ambient oxygen, and the controller manages the entire calibration process without requiring external equipment or complex user intervention

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent extracts the essential calibration function from external reference equipment and implements it within the sensor itself. By taking out only the critical UV photolysis function and integrating it into the sensor device, the system achieves calibration capability without the burden of substantial external equipment

Inventive Principle:
Principle #2Taking out (Extraction)

3Device complexity

If target gas is generated in controllable and miniaturized manner, then device complexity is reduced, but measurement precision may deteriorate without reference equipment

Engineering Contradiction:
Improvecalibration system sizeVSAvoidcalibration accuracy
Core Design Contradiction:
Device complexityVSMeasurement precision

Solution Approach 1:

The UV light source serves as an intermediary that enables miniaturized, controllable ozone generation. By using photolytic decomposition of oxygen, the system achieves precise control over ozone production in a compact form factor, maintaining calibration accuracy without reference equipment

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces mechanical ozone generation systems with a phot化学ical approach. The UV light source substitutes for complex mechanical ozone generators, enabling miniaturized and controllable ozone production through photolytic decomposition of oxygen

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Productivity

If MOX sensor is used for ozone detection, then productivity is improved, but reliability deteriorates due to chemical poisoning and deactivation causing drift

Engineering Contradiction:
Improvedetection speedVSAvoidcalibration stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The system performs preliminary calibration actions by generating ozone before actual measurements. The UV light source pre-generates calibration gas to establish baseline readings, and the controller uses this information to compensate for drift during subsequent measurements

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent implements feedback-based drift compensation. The sensor periodically measures its own response to UV-generated ozone, and the controller adjusts calibration parameters based on detected drift, maintaining reliability while preserving the fast response characteristics of MOX sensors

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method allows for reliable and practical in-sensor span calibration of MOX sensors, reducing calibration drift and enhancing their performance in consumer electronics, even when generating a zero-target-gas condition is challenging, by using co-located sensors and modeling various environmental factors.

Implementation Method 1

In-sensor span calibration can be facilitated by using a light source to generate ozone gas from the air inside a gas-sensing device

Methodology Applied
Scientific EffectPhotodissociation: Photodissociation

Implementation Method 2

When heated to the working temperature, the resistance of the metal oxide material changes with the gas environment and concentration. The target gas can be an oxidizing gas such as ozone (O3) or nitrogen oxide (NOx), which increases MOX resistance.

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

The target gas may be a reducing gas, for example, hydrogen (H2) or volatile organic compounds (VOC), which decreases the MOX resistance.

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 4

Many MOX gas sensors consist of a porous MOX material dispensed on a micro-hotplate, which is used to regulate temperature. When heated to the working temperature, the resistance of the metal oxide material changes

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Data Source

PatentUS10928345B2In-sensor span calibration for MEMS ozone sensor
Publication Date: 2021.02.23 APPLE INC
  • US10928345B2 patent drawing
  • US10928345B2 patent drawing
  • US10928345B2 patent drawing

AI summary

A portable communication device may include a gas sensor enclosed in an enclosure, a port to allow flow of air into and out of the enclosure, and a light source disposed on an internal surface of the enclosure. The light source is operable to facilitate generation of ozone gas within the enclosure. The enclosure may contain a heating element that allows baseline calibration of the gas sensor by thermally decomposing ozone gas molecules. The gas sensor includes a miniature gas sensor such as a metal-oxide (MOX) gas sensor.