Mesogenic Epoxy Compound for Semiconductor Heat Dissipation

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Solution Overview

Problem

Existing epoxy molding compounds (EMCs) with high-thermal-conductivity inorganic fillers fail to significantly enhance thermal conductivity, limiting the heat dissipation capabilities of semiconductor packages.

Innovation Solution

Incorporation of an epoxy compound with an aromatic ring structure, featuring a mesogenic unit and a spacer, which enhances phonon transfer pathways and suppresses scattering, resulting in improved thermal conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If high-thermal-conductivity inorganic filler is added to EMC, then thermal conductivity is expected to increase, but the increase is insignificant

Engineering Contradiction:
Improvethermal conductivityVSAvoidheat dissipation capability
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The invention changes the chemical structure parameters of the epoxy compound by introducing aromatic rings, mesogenic units, and spacers. This structural modification alters the thermal properties of the resin itself, enabling phonon transfer pathways that significantly enhance thermal conductivity from the base material level, rather than relying solely on filler addition.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite structure at the molecular level by combining aromatic rings, mesogenic units, and spacers within the epoxy compound architecture. This multi-component molecular composite enables synergistic effects where the aromatic rings provide thermal conduction pathways, mesogenic units organize molecular alignment, and spacers optimize the structural arrangement for phonon transfer.

Inventive Principle:
Principle #40Composite materials

2Temperature

If conventional epoxy resin is used, then processing characteristics are maintained, but heat releasing characteristics are insufficient

Engineering Contradiction:
Improveheat release characteristicsVSAvoidprocessing characteristics
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The invention modifies the epoxy compound structure by incorporating aromatic rings, mesogenic units, and spacers, which changes the thermal parameters while maintaining processability. The molecular weight and functional group distribution are optimized to ensure the compound remains workable during manufacturing while achieving superior heat dissipation in the cured state.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If inorganic filler is added to improve thermal conductivity, then thermal stability is expected to improve, but the effect is limited

Engineering Contradiction:
Improvethermal stabilityVSAvoidmaterial composition complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The invention changes the fundamental thermal parameters of the epoxy compound by introducing aromatic rings, mesogenic units, and spacers. This approach improves thermal stability through intrinsic molecular properties rather than relying on filler addition, thereby achieving better thermal performance with simpler material composition and fewer processing steps.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The epoxy compound and its cured products exhibit significantly increased thermal conductivity, up to 18 W/mK, enhancing the thermal stability and heat release characteristics of semiconductor devices.

Implementation Method 1

Incorporation of an epoxy compound with an aromatic ring structure, featuring a mesogenic unit and a spacer, which enhances phonon transfer pathways and suppresses scattering, resulting in improved thermal conductivity.

Methodology Applied
Scientific EffectPhonon transfer: Conduction (thermal)

Data Source

PatentEP4015556B1Epoxy compound, composition prepared therefrom, semiconductor device prepared therefrom, electronic device prepared therefrom, article prepared therefrom, and method of preparing epoxy compound
Publication Date: 2026.03.11 SAMSUNG ELECTRONICS CO LTD
  • EP4015556B1 patent drawingFigure 1~2
  • EP4015556B1 patent drawingFigure 3
  • EP4015556B1 patent drawingFigure 4

AI summary

An epoxy compound having an aromatic ring represented by Formula 1 or Formula 2, a composition prepared from the epoxy compound, a semiconductor device prepared from the epoxy compound, an electronic device prepared from the epoxy compound, an article prepared from the epoxy compound, and a method of preparing the epoxy compound:          Formula 1     E1-(M1)a1-(L1)b1-(M2)a2-L2-A1-L3-(M3)a3-(L4)b2-(M4)a4-E2          Formula 2     E3-(A2)c1-(L5)b3-(M5)a5-L6-(M6)a6-L7-(M7)a7-(L8)b4-(A3)c2-E4 In Formulae 1 and 2, M1, M2, M3, M4, M5, M6, M7, A1, A2, A3, L1, L2, L3, L4, L5, L6, L7, L8, E1, E2, E3, E4, a1, a2, a3, a4, a5, a6, a7, b1, b2, b3, b4, c1, and c2 are the same as defined in the detailed description.