Mesoporous Silica Nanoparticle Antireflection Coating

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Solution Overview

Problem

Conventional antireflection materials face issues with degradation and breakage due to thermal expansion or mechanical deformation of the resin base member, and they are difficult to apply to curved or complex surfaces due to the need for precise control of film thickness and porosity.

Innovation Solution

An antireflection member comprising a resin base member with a particle layer of mesoporous-silica nanoparticles directly fixed and partially embedded, forming a mono-particle layer, which enhances wear resistance and durability, and a transfer member for efficient application to complex shapes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a continuous film made of antireflection coating layer is formed on resin base member, then antireflection performance is improved, but the coating layer degrades or breaks when heated or subjected to external force

Engineering Contradiction:
Improveantireflection performanceVSAvoidcoating layer durability
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The continuous film is segmented into discrete nanoparticles arranged in a mono-particle layer. These particles are at least partially embedded in the resin base member surface, creating a structure that maintains antireflection performance while being more resistant to degradation and breakage under thermal or mechanical stress.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates a composite structure combining resin base member with embedded nanoparticle layer. The nanoparticles (at least partially embedded) form a hybrid structure with the resin, providing both optical functionality and mechanical/thermal durability that neither material achieves alone.

Inventive Principle:
Principle #40Composite materials

2Reliability

If film thickness is strictly controlled to obtain desired optical characteristics, then antireflection performance is improved, but production complexity increases and application to curved surfaces becomes difficult

Engineering Contradiction:
Improveoptical characteristicsVSAvoidproduction control complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention changes the control parameter from continuous film thickness to discrete nanoparticle size and spacing. By controlling nanoparticle diameter (50-300 nm) and arrangement in a mono-particle layer, the desired optical characteristics are achieved without the need for precise thickness control of a continuous film, simplifying production and enabling application to curved surfaces.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If porosity of matrix portion is increased to improve antireflection performance, then optical characteristics are improved, but mechanical strength decreases

Engineering Contradiction:
Improveantireflection performanceVSAvoidmatrix strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The invention extracts the porosity function from the matrix material itself and relocates it to discrete mesoporous silica nanoparticles. The nanoparticles provide the necessary porosity (40-70%) for antireflection performance, while the resin matrix maintains its mechanical strength without needing to be porous.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a durable antireflection member with improved wear resistance and optical performance, capable of being applied to curved or complex surfaces without the need for precise thickness control, ensuring effective antireflection and mechanical stability.

Implementation Method 1

the nanoparticles are at least partially embedded in the surface of the resin base member

Methodology Applied
Scientific EffectPhysical embedding:

Implementation Method 2

a particle layer comprising mesoporous-silica nanoparticles directly fixed to a surface of the resin base member... arranged in a mono-particle layer to form the particle layer

Methodology Applied
Scientific EffectLight absorption and scattering: Absorption (EM radiation)

Data Source

PatentUS10451771B2Antireflection member, transfer member, and method for producing antireflection member
Publication Date: 2019.10.22 KK TOYOTA CHUO KENKYUSHO
  • US10451771B2 patent drawing
  • US10451771B2 patent drawing
  • US10451771B2 patent drawing

AI summary

An antireflection member, including a resin base member; and a particle layer having mesoporous-silica nanoparticles directly fixed to a surface of the resin base member, wherein the nanoparticles are at least partially embedded in the surface of the resin base member, and the nanoparticles are arranged in a mono-particle layer to form the particle layer.