Interpenetrating Metal Composite Mesh for High-Resolution Infiltration

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Solution Overview

Problem

Existing additive manufacturing processes for metal/metal interpenetrating phase composites suffer from low printing resolution and the formation of brittle intermetallics due to thermal stresses, limiting the production of high-quality, functionally graded parts.

Innovation Solution

A method involving the formation of a preform with a three-dimensional open-cell mesh structure using additive manufacturing, followed by preheating and infiltration with a liquid metal of lower melting point to create a solid matrix, avoiding the formation of brittle intermetallics and enabling higher resolution and tailored mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If fusion-based additive manufacturing is used to print metal/metal interpenetrating phase composites by changing feedstock composition during printing, then complex geometries can be fabricated, but printing resolution becomes low and brittle intermetallics form due to thermal stresses

Engineering Contradiction:
Improveability to fabricate complex geometriesVSAvoidprinting resolution
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The fabrication process is segmented into two distinct stages: (1) printing a porous preform structure with one metal using additive manufacturing, and (2) infiltrating the preform with a second liquid metal. This segmentation allows the first metal to form a robust scaffold at high resolution, while the second metal fills the pores without experiencing the same thermal stress issues, thereby achieving both complex geometries and high printing resolution simultaneously

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The preform structure is prepared in advance through additive manufacturing before the infiltration step. This preliminary action creates a precisely controlled porous scaffold that defines the final composite geometry. By pre-forming the structure with high resolution before introducing the second metal, the method achieves both high printing resolution and the ability to create complex geometries

Inventive Principle:
Principle #10Preliminary action

2Adaptability or versatility

If fusion-based additive manufacturing is used to print metal/metal interpenetrating phase composites, then complex objects can be created, but brittle intermetallics form and crack due to thermal stresses from the heat source

Engineering Contradiction:
Improveability to create complex objectsVSAvoidstructural integrity of intermetallics
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The method changes the physical state parameter of the second metal from solid to liquid during infiltration. By introducing the second metal in liquid form at temperatures below the melting point of the first metal, thermal stresses are avoided and brittle intermetallic formation is prevented. The liquid metal infiltrates the preform and solidifies without experiencing the thermal cycling that causes cracking in fusion-based processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The porous preform structure acts as an intermediary between the two metals. It provides a stable scaffold that prevents direct fusion and intermetallic formation between the two metal phases. The preform mediates the interaction by allowing liquid metal infiltration while maintaining structural integrity, thereby preventing the formation of brittle intermetallic compounds

Inventive Principle:
Principle #24Intermediary (Mediator)

3Adaptability or versatility

If feedstock composition is changed during printing to create interpenetrating phase composites, then composite structures can be formed, but the process suffers from low printing resolution

Engineering Contradiction:
Improveability to form composite structuresVSAvoidprinting resolution
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The composite formation process is segmented into two steps: first printing a preform with one metal at high resolution, then infiltrating with a second liquid metal. This segmentation eliminates the need to change feedstock composition during printing, thereby maintaining high printing resolution while still forming complex interpenetrating phase composite structures

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The preform structure is preliminarily formed with high printing resolution using additive manufacturing before the infiltration step. This preliminary high-resolution printing of the scaffold structure, followed by liquid metal infiltration, achieves both composite structure formation and high manufacturing precision without the resolution losses associated with changing feedstock composition during printing

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves higher resolution patterning and improved mechanical properties, including increased strain to failure and tailored physical/mechanical properties on both global and local scales, without the formation of brittle intermetallics, thus overcoming the limitations of fusion-based additive manufacturing.

Implementation Method 1

pre-heating the preform to a first temperature less than the melting point of the first metal

Methodology Applied
Scientific EffectThermal heating: Heating

Implementation Method 2

infiltrating the preform with a second metal in liquid form. The second metal has a melting point lower than the melting point of the first metal. The method also includes allowing the second metal to cool and form a solid matrix

Methodology Applied
Scientific EffectPhase change from liquid to solid: Freezing

Data Source

PatentUS11325206B2Additive manufactured interpenetrating phase composite
Publication Date: 2022.05.10 UT BATTELLE LLC
  • US11325206B2 patent drawing
  • US11325206B2 patent drawing
  • US11325206B2 patent drawing

AI summary

A method for preparing metal/metal interpenetrating phase composites is provided. The method includes forming a preform using additive manufacturing. The preform defines a materially continuous three-dimensional open-cell mesh structure. The preform includes a first metal having a melting point. The method further includes pre-heating the preform to a first temperature less than the melting point of the first metal. The method includes infiltrating the preform with a second metal in liquid form. The second metal has a melting point lower than the melting point of the first metal. The method also includes allowing the second metal to cool and form a solid matrix. The solid matrix defines a continuous material network.