Metal Compound Charge Control Agent Residue Deposition

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Solution Overview

Problem

Metal complexes used as charge control agents in electrostatic printing can decompose during thermal treatment, leading to residue deposition in printing devices, which inhibits the toner development process and causes migration issues.

Innovation Solution

A metal compound with aromatic hydroxycarboxylic acid structures bonded to a polymer segment, which inhibits the migration and decomposition of residues by forming a stable bond, reducing deposition and maintaining charge control efficacy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If metal complexes of aromatic hydroxycarboxylic acid are used as charge control agents, then charge control efficacy is improved, but residue deposition and migration occur during thermal treatment

Engineering Contradiction:
Improvecharge control efficacyVSAvoidresidue deposition
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies composite materials by combining the metal complex of aromatic hydroxycarboxylic acid with a polymer segment to form a hybrid charge control agent. This composite structure integrates the charge control functionality of the metal complex with the stabilizing and binding properties of the polymer, preventing residue deposition and migration while maintaining effective charge control in the toner composition.

Inventive Principle:
Principle #40Composite materials

2Reliability

If metal complexes are used for charge control, then toner chargeability is improved, but decomposition occurs during thermal treatment

Engineering Contradiction:
Improvetoner chargeabilityVSAvoidchemical stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The polymer segment acts as an intermediary between the metal complex and the thermal environment. It provides a protective matrix that stabilizes the metal complex during thermal treatment, preventing decomposition while allowing the complex to maintain its charge control functionality. The polymer mediates the interaction between the heat and the sensitive metal complex.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If aromatic hydroxycarboxylic acid metal complexes are used, then charge control performance is enhanced, but migration through substrate occurs

Engineering Contradiction:
Improvecharge control performanceVSAvoidsubstrate migration
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent merges the aromatic hydroxycarboxylic acid metal complex with a polymer segment to create a unified charge control agent. This merging prevents the complex from migrating through the substrate by integrating it into a larger molecular structure where the polymer portion anchors the complex in place, eliminating the harmful migration effect while preserving charge control performance.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The metal compound effectively reduces residue deposition and migration within electrostatic printing devices while maintaining suitable charging behavior, enhancing the stability and performance of the toner composition.

Implementation Method 1

each aromatic hydroxycarboxylic acid structure having an aromatic moiety having a hydroxyl substituent and a carboxylic acid substituent, which cooperatively bond the aromatic moiety to the metal via at least one of ionic bond, covalent bond and coordinate bond

Methodology Applied
Scientific EffectCoordinate bond: Chemical Bonding

Implementation Method 2

wherein each aromatic hydroxycarboxylic acid structure is bonded to a polymer segment

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 3

A charge control agent composition is known to be used to provide a positive or a negative charge to a toner composition for developing electrostatic images

Methodology Applied
Scientific EffectElectrostatic charge: Electrostatics

Data Source

PatentUS11573500B2Metal compound, use of the metal compound as a charge control agent composition and a chargeable toner composition
Publication Date: 2023.02.07 XEIKON MFG NV
  • US11573500B2 patent drawing
  • US11573500B2 patent drawing
  • US11573500B2 patent drawing

AI summary

A metal compound includes a metal and at least two aromatic hydroxycarboxylic acid structures. Each aromatic hydroxycarboxylic acid structure includes an aromatic moiety having a hydroxyl substituent and a carboxylic acid substituent, which cooperatively bond the aromatic moiety to the metal via at least one of ionic bond, covalent bond and coordinate bond. Each aromatic hydroxycarboxylic acid structure is bonded to a polymer segment.