Metal Foam Alloy Formation Control

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Solution Overview

Problem

Existing processes for producing metal foam bodies often result in alloy formation extending beyond the desired upper layers, leaving unalloyed regions in central regions, which is crucial for maintaining chemical and mechanical stability in applications like catalyst technology.

Innovation Solution

A process involving a metal foam body composed of two metallic components, treated with a metal-containing powder and subjected to a thermal treatment within specific temperature and duration ranges (680-715°C for 5-240 seconds) to limit alloy formation to the upper layers, using combinations like nickel and cobalt or aluminium and chromium, followed by a basic solution treatment to remove excess components.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If thermal treatment is performed at high temperatures for extended periods to ensure complete alloy formation, then alloy formation is improved, but alloy formation extends into deeper regions of the metal foam creating unwanted unalloyed regions

Engineering Contradiction:
Improvecontrol of alloy formation depthVSAvoidchemical and mechanical stability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies parameter changes by precisely controlling thermal treatment parameters (temperature between 680-715°C and duration between 5-240 seconds) to limit alloy formation to only the upper layers of the metal foam. This controlled parameter regime creates a gradient where the outer surface develops alloy layers while the central regions remain unalloyed, achieving the desired manufacturing precision for catalyst support structures.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If thermal treatment is performed at lower temperatures to limit alloy formation to upper regions, then unalloyed regions are preserved in central regions, but alloy formation may be insufficient in the contact region

Engineering Contradiction:
Improvechemical and mechanical stabilityVSAvoidcontrol of alloy formation depth
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent resolves this contradiction by optimizing the thermal treatment parameter window to 680-715°C for 5-240 seconds. This specific parameter range is sufficient to create adequate alloy formation in the contact region for mechanical stability while simultaneously limiting diffusion to prevent unwanted alloying in deeper regions, thus preserving the chemically stable unalloyed metal foam core.

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If metal powders are applied to metal foam bodies to form alloys, then catalytic activity is improved, but alloy formation may extend beyond desired regions

Engineering Contradiction:
Improvecatalytic activityVSAvoidcontrol of alloy formation depth
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent applies local quality by creating spatially differentiated regions within the metal foam body. The outer surface layers develop alloy compositions with enhanced catalytic activity through metal powder application, while the central regions maintain the original unalloyed metal foam structure. This local differentiation allows the catalyst to exhibit both high catalytic activity at the surface and structural integrity from the unalloyed core.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process ensures that unalloyed regions remain in the central regions of the metal foam, enhancing its chemical and mechanical stability, and allows for the production of metal foam bodies suitable for catalysts and support components.

Implementation Method 1

treating metal foam body AX thermally in order to achieve alloy formation between the metallic components of metal foam body A and the metal-containing powder MP

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

the thermal treatment for alloy formation is followed by a treatment with a basic solution

Methodology Applied
Scientific EffectChemical dissolution:

Data Source

PatentUS12076790B2Metal foam bodies and process for production thereof
Publication Date: 2024.09.03 EVONIK OPERATIONS GMBH

AI summary

The present invention relates to processes for producing metal foam bodies, in which metal-containing powders that may comprise aluminium and chromium or molybdenum are applied to metal foam bodies that may comprise nickel, cobalt, copper and iron and then treated thermally, wherein the highest temperature in the thermal treatment of the metal foam bodies is in the range from 680 to 715° C., and wherein the total duration of the thermal treatment within the temperature range from 680 to 715° C. is between 5 and 240 seconds. Following this method of thermal treatment can achieve alloy formation at the contact surface between metal foam body and metal-containing powder, but simultaneously leave unalloyed regions within the metal foam. The present invention further comprises processes comprising the treatment of the alloyed metal foam bodies with basic solution. The present invention further comprises the metal foam bodies obtainable by these processes, which find use, for example, as support and structure components and in catalyst technology.