Metal Foam Catalyst Structure With Surface Alloying Stability

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Solution Overview

Problem

Existing methods for producing Raney metal catalysts as fixed-bed catalysts face challenges in achieving mechanical stability and require costly sedimentation and filtration processes due to the need for removing leachable components, and there is a need to limit alloy formation to specific regions of metal foams to maintain mechanical stability.

Innovation Solution

A process involving thermal treatment of metal foam bodies with an aluminum-containing material under controlled temperature and duration conditions to limit alloy formation to the upper layers, leaving unalloyed regions in the central parts, ensuring mechanical stability and chemical stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If thermal treatment is extended to achieve complete alloy formation, then catalytic activity is improved, but mechanical stability deteriorates

Engineering Contradiction:
Improvecatalytic activityVSAvoidmechanical stability
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies local quality by creating different alloying degrees in different regions of the metal foam. The thermal treatment is controlled so that alloy formation occurs primarily in the outer layers where catalytic activity is needed, while the inner core remains unalloyed to provide mechanical stability. This spatial differentiation of material properties resolves the contradiction between catalytic activity and mechanical stability.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs partial action by intentionally limiting the alloy formation process to only the extent needed for catalytic functionality. Rather than achieving complete alloy formation throughout the entire metal foam, the treatment is controlled to create a gradient where alloying is concentrated in specific regions, leaving sufficient unalloyed metal to maintain structural integrity.

Inventive Principle:
Principle #16Partial or excessive action

2Reliability

If pulverulent Raney metal catalysts are used for catalysis, then catalytic activity is improved, but separation and removal become costly and complex

Engineering Contradiction:
Improvecatalytic activityVSAvoidseparation process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent utilizes porous metal foam as the catalyst support structure. This porous material provides high surface area for catalytic reactions while maintaining a fixed-bed form that enables simple separation. The porous structure allows reactants to access the catalytically active alloyed regions while the overall foam structure remains mechanically stable and easily separable from reaction mixtures.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent creates a composite catalyst system combining alloyed outer layers with unalloyed inner core in a foam structure. This composite material integrates the high catalytic activity of alloyed Raney metal with the mechanical stability and ease of handling of foam structure, eliminating the need for complex separation processes required for pulverulent catalysts.

Inventive Principle:
Principle #40Composite materials

3Reliability

If alloy formation is extended to deeper regions of metal foam, then catalytic activity is improved, but mechanical stability deteriorates

Engineering Contradiction:
Improvecatalytic activityVSAvoidmechanical stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies local quality by creating different alloying degrees in different regions of the metal foam. The thermal treatment is controlled so that alloy formation occurs primarily in the outer layers where catalytic activity is needed, while the inner core remains unalloyed to provide mechanical stability. This spatial differentiation of material properties resolves the contradiction between catalytic activity and mechanical stability.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process allows for the production of metal foam catalysts with controlled alloy formation, maintaining mechanical stability and enhancing chemical stability, suitable for use in catalytic reactions.

Implementation Method 1

treating metal foam bodies AX thermally, with exclusion of oxygen, in order to achieve alloy formation between the metallic components of metal foam body A and the aluminum-containing material MP

Methodology Applied
Scientific EffectAlloy formation: Diffusion Welding

Implementation Method 2

treating metal foam bodies AX thermally, with exclusion of oxygen, in order to achieve alloy formation

Methodology Applied
Scientific EffectThermal treatment: Heat Treatment

Data Source

PatentUS12551871B2Metal-foam body and method for the production thereof and the use thereof as a catalyst
Publication Date: 2026.02.17 EVONIK OPERATIONS GMBH
  • US12551871B2 patent drawing

AI summary

The invention relates to a method for producing a metal-foam body, comprising the steps of (a) providing a metal-foam body A, which consists of nickel, cobalt, copper, or alloys or combinations thereof, (b) applying an aluminum-containing material MP to metal-foam body A so as to obtain metal-foam body AX, (c) thermally treating of metal-foam body AX, with the exclusion of oxygen, to achieve the formation of an alloy between the metallic components of metal-foam body A and the aluminum-containing material MP so as to obtain metal-foam body B, wherein the duration of the thermal treatment is chosen in dependence on the temperature of the thermal treatment and the temperature of the thermal treatment is chosen in dependence on the thickness of the metal-foam body AX. The invention also relates to the metal-foam bodies obtainable by the methods according to the invention and to the use thereof as catalysts for chemical transformations.