Metal-Free Antioxidant Composition for Lubricating Oil Stability

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Solution Overview

Problem

Current antioxidant compositions for lubricating oils do not achieve high anti-oxidation performance, especially at varying temperatures, and the disposal of metal-containing lubricating oils poses environmental concerns, while existing combinations of non-metal antioxidants have not met the demand for extended shelf life and high performance.

Innovation Solution

A synergistic antioxidant composition combining a specific phenol-based compound with a general amine-based or phenol-based antioxidant, with a weight ratio of 30/70 to 99/1, which does not contain metal elements, enhancing the anti-oxidation performance of lubricating oils without compromising stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If metal-containing antioxidants are used to improve anti-oxidation performance, then the anti-oxidation performance is improved, but environmental harm increases due to heavy metal disposal costs

Engineering Contradiction:
Improveanti-oxidation performanceVSAvoidenvironmental harm from metal disposal
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention extracts and removes metal elements from the antioxidant system, replacing them with non-metallic organic compounds. The patent specifically uses phenol-based and amine-based antioxidants without any metal content, thereby eliminating the environmental harm associated with metal disposal while maintaining anti-oxidation functionality.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical composition parameters of the antioxidant from metal-containing to metal-free organic compounds. By adjusting the molecular structure and chemical properties of the organic antioxidants, the patent achieves high anti-oxidation performance without the harmful environmental effects of metal additives.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If existing non-metal antioxidant combinations are used to avoid environmental harm, then environmental harm is reduced, but anti-oxidation performance is insufficient

Engineering Contradiction:
Improveenvironmental harm from metal disposalVSAvoidanti-oxidation performance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The invention merges phenol-based antioxidants and amine-based antioxidants into a synergistic combination. The patent specifies that both types of antioxidants are present in the composition, leveraging their complementary mechanisms to achieve superior anti-oxidation performance that neither could achieve alone, while maintaining metal-free environmental benefits.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention creates a composite antioxidant system using multiple organic compounds with different chemical structures and mechanisms. The combination of phenol-based and amine-based antioxidants forms a composite material that provides enhanced and synergistic anti-oxidation protection, meeting high performance requirements without metal content.

Inventive Principle:
Principle #40Composite materials

3Device complexity

If single-type antioxidants are used to simplify the composition, then device complexity is reduced, but anti-oxidation performance across varying temperatures is insufficient

Engineering Contradiction:
Improveantioxidant composition complexityVSAvoidanti-oxidation performance at varying temperatures
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The invention designs the antioxidant composition to perform multiple functions across different temperature conditions. The phenol-based and amine-based antioxidants work synergistically to provide effective protection across a wide temperature range, making the composition universally effective for various operating conditions without requiring separate antioxidant systems for different temperatures.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The antioxidant composition extends the shelf life of lubricating oils by providing excellent anti-oxidation performance and stability, free from metal elements, thus addressing the environmental concerns associated with metal-containing additives.

Implementation Method 1

an antioxidant composition, free of any metal element, which has high anti-oxidation performance... including: a compound (A) represented by the following general formula (1); and an amine-based antioxidant (B) and a phenol-based antioxidant (C)

Methodology Applied
Scientific EffectAntioxidation: Oxidation

Data Source

PatentEP2617802B1Antioxidant composition, and lubricating oil composition containing same
Publication Date: 2019.09.18 ADEKA CORP
  • EP2617802B1 patent drawing
  • EP2617802B1 patent drawing
  • EP2617802B1 patent drawing

AI summary

Provided is an antioxidant composition, including: a compound (A) represented by the following general formula (1); and an amine-based antioxidant (B) and/or a phenol-based antioxidant (C) other than the compound (A): (wherein R represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and n represents a number from 1 to 3.)