Metal-Free Textile Dyes for Higher NIR Reflectance

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Solution Overview

Problem

Existing textile materials, especially those dyed for aesthetic or technical reasons, tend to absorb and retain heat due to solar radiation, leading to discomfort, and conventional NIR-reflecting coatings often contain metal particles that compromise wearing comfort and handle.

Innovation Solution

Dyeing textile materials with metal-free dyes that maintain or increase Near Infrared (NIR) reflectance in the 700 nm to 1100 nm range using customary dyeing processes, specifically using acid, basic, disperse, or reactive dyes with defined structures, to minimize heat absorption without affecting the material's comfort or handle.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional coatings with metal particles are used to reflect thermal radiation, then NIR reflectance is improved, but wearing comfort and handle deteriorate

Engineering Contradiction:
ImproveNIR reflectanceVSAvoidwearing comfort
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

The invention extracts and eliminates metal particles from the coating composition, retaining only the binder system that provides NIR reflection. This removes the harmful component (metal particles affecting comfort) while preserving the useful function (NIR reflection through binder).

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the chemical composition parameters of the coating by selecting specific binder systems with appropriate NIR reflection properties and eliminating metal particle additives. This parameter change achieves NIR reflection without the negative effects of metal particles on wearing comfort.

Inventive Principle:
Principle #35Parameter changes

2Illumination intensity

If dark coloured textile materials are used for aesthetic reasons, then appearance is improved, but heat absorption increases

Engineering Contradiction:
Improveaesthetic appearanceVSAvoidheat absorption
Core Design Contradiction:
Illumination intensityVSTemperature

Solution Approach 1:

The invention applies local quality by differentiating the optical properties at different wavelengths: the dye provides absorption in the visible range (aesthetic appearance) while the binder system provides reflection in the NIR range (heat reflection). This local differentiation of optical properties resolves the contradiction between appearance and heat absorption.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention creates a composite optical system where the dyed textile material combines dye molecules (for visible color) with a NIR-reflecting binder system. This composite structure enables simultaneous achievement of aesthetic appearance through dye and heat reflection through the binder.

Inventive Principle:
Principle #40Composite materials

3Loss of energy

If metal-containing coatings are applied to reduce solar absorption, then thermal radiation reflection is improved, but textile handle and comfort deteriorate

Engineering Contradiction:
Improvesolar absorptionVSAvoidtextile handle
Core Design Contradiction:
Loss of energyVSEase of operation

Solution Approach 1:

The invention extracts metal particles from the coating formulation, relying solely on the binder system to provide thermal radiation reflection. This extraction eliminates the harmful effect on textile handle while maintaining the energy reflection function.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention replaces expensive and harmful metal particles with an organic binder system that achieves the same functional effect (NIR reflection) without the negative side effects. The binder acts as a temporary coating that provides the needed protection without compromising textile properties.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process effectively reduces heat absorption, enhancing wearing comfort by maintaining or increasing NIR reflectance, thus reducing thermal radiation absorption, while preserving the textile's properties and comfort.

Implementation Method 1

dyed textile materials having, compared with the same, undyed textile materials, an increased or at least equivalent reflectance of electromagnetic radiation in the near infrared (NIR), in particular dyed textile materials having increased or at least equivalent reflectance of electromagnetic radiation in the region of electromagnetic radiation of wavelength 700 nm to 1100 nm

Methodology Applied
Scientific EffectNear infrared reflectance: Reflection

Data Source

PatentEP2262945B1Influencing the near infrared reflectance of dyed textile materials
Publication Date: 2013.03.13 CLARIANT FIANCE (BVI) LTD
  • EP2262945B1 patent drawing
  • EP2262945B1 patent drawing
  • EP2262945B1 patent drawing

AI summary

Use of the customary dyes for the type of fibre in question and using the customary dyeing and/or printing processes for the type of fibre in question for minimally reducing, retaining or increasing the NIR reflectance, preferably increasing the NIR reflectance, in the region of electromagnetic radiation of wavelength 700 nm to 1100 nm of textile material in relation to the undyed and untreated textile material, characterized in that metal-free dyes are used.