Metal Interconnect Rework Using Etch and Thermal Anneal

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Solution Overview

Problem

The challenge in the BEOL copper interconnect structures is the presence of defects such as voids, under-fill, and recesses, which lead to loss of line yield and circuit failures, especially at advanced nodes, where patterning becomes increasingly difficult.

Innovation Solution

A method involving selective etching and reflow of the metal interconnect layer within trenches, followed by deposition of a second diffusion barrier liner and additional metal interconnect layers, allowing for planarization and addressing defects without requiring additional patterning steps, and applicable at any interconnect level before or after planarization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional BEOL processing with copper interconnects is used, then electrical resistance is reduced and conduction is improved, but defects such as voids, recesses and under-fill occur leading to line yield loss and circuit failures

Engineering Contradiction:
Improveline yieldVSAvoidinterconnect defect rate
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the material parameter from copper to cobalt for the interconnect structure. Cobalt provides both low electrical resistance and superior fill characteristics that eliminate voids and under-fill defects. The cobalt interconnect structure maintains electrical performance while achieving complete trench filling without the defects associated with copper processing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a sacrificial mandrel structure that is intentionally designed to be temporary and removable. The mandrel serves its purpose during deposition and etching, then is completely removed to leave clean, defect-free interconnect trenches. This disposable approach allows for precise control of the interconnect formation process without leaving residual defects

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Reliability

If copper interconnects are used in BEOL structures, then electrical performance is improved, but additional patterning steps are required to address defects

Engineering Contradiction:
Improvecircuit performanceVSAvoidpatterning steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent changes the material parameter from copper to cobalt, which fundamentally alters the processing requirements. Cobalt's material properties enable direct deposition and self-aligned etching processes that eliminate the need for additional patterning steps. The cobalt interconnect structure achieves both electrical performance and process simplification simultaneously

Inventive Principle:
Principle #35Parameter changes

3Reliability

If metal interconnect layers are deposited to fill trenches, then interconnect continuity is achieved, but voids and under-fill defects remain

Engineering Contradiction:
Improveinterconnect continuityVSAvoidtrench fill quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the material parameter from copper to cobalt, which has superior wetting and fill characteristics. Cobalt deposits conformally and completely fills trenches without forming voids or under-fill defects. The material parameter change fundamentally improves the fill quality while maintaining interconnect continuity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a sacrificial mandrel that is removed after serving its deposition template function. This removable mandrel approach ensures complete trench filling by the cobalt interconnect material while leaving no residual structures that would cause voids or under-fill defects

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces defects in metal interconnects, improves line yield, and minimizes wafer scrap by ensuring void-free metal accumulation at the bottom of trenches and planarization, thus enhancing the reliability of the BEOL structures.

Implementation Method 1

The first metal interconnect layer within the trenches is etched to open the voids therein

Methodology Applied
Scientific EffectEtching:

Implementation Method 2

The first metal interconnect layer within the trenches is etched to open the voids therein and then reflowed

Methodology Applied
Scientific EffectThermal anneal: Annealing

Implementation Method 3

then reflowed, thereby forming a bottom interconnect layer portion within each of the trenches

Methodology Applied
Scientific EffectReflow:

Implementation Method 4

A second diffusion barrier liner is formed on the opposing sidewalls of the trenches above the bottom interconnect layer portions

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Implementation Method 5

A second metal interconnect layer is deposited within the trenches on the bottom interconnect layer portions and between opposing portions of the second diffusion barrier liner

Methodology Applied
Scientific EffectMetal deposition: Physical Vapour Deposition

Implementation Method 6

The second metal interconnect layer is then planarized

Methodology Applied
Scientific EffectPlanarization:

Data Source

PatentUS11901224B2Rework for metal interconnects using etch and thermal anneal
Publication Date: 2024.02.13 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US11901224B2 patent drawing
  • US11901224B2 patent drawing
  • US11901224B2 patent drawing

AI summary

Metal interconnect structures are reworked to address possible voids or other defects. Etching of initially deposited interconnect metal to open voids is followed by reflow to accumulate interconnect metal at the bottoms of trenches. Additional interconnect metal is deposited over the initially deposited interconnect metal by electroplating and/or electroless plating. Additional diffusion barrier material may be deposited and patterned prior to deposition of the additional interconnect material.