Metal Methacrylate Sealing Layer for Moisture Protection

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Solution Overview

Problem

Electronic devices such as OLEDs, LCDs, LEDs, OPV cells, and organic thin film transistors are vulnerable to oxygen and moisture, leading to deterioration and a need for an effective seal to maintain their quality.

Innovation Solution

An organic film forming composition is developed, comprising a metal (meth)acrylate and a curable material, which forms a sealing layer with alternating organic and inorganic films to prevent moisture permeation, utilizing the metal (meth)acrylate's ability to adsorb water molecules through hydrogen bonding or ion-dipole interactions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a sealing layer is applied to protect electronic devices from moisture and oxygen, then the device reliability is improved, but the complexity of the device structure increases

Engineering Contradiction:
Improvedevice reliabilityVSAvoiddevice structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The sealing structure is divided into multiple alternating layers of organic material and inorganic material, where each layer performs specific protective functions. The organic layers provide flexibility and adhesion while the inorganic layers provide barrier properties, collectively achieving comprehensive protection without requiring a single complex sealing component.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs composite material structure combining organic and inorganic layers to create a sealing system that leverages the complementary properties of both material types. The organic-inorganic composite structure provides enhanced moisture and oxygen barrier performance while maintaining mechanical flexibility, resolving the contradiction between protection effectiveness and structural simplicity.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the sealing layer uses materials with high moisture-adsorbing ability, then the hygroscopic properties are improved, but the moisture permeation prevention capability may be compromised

Engineering Contradiction:
Improvehygroscopic propertiesVSAvoidmoisture permeation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent converts the typically harmful moisture adsorption property into a beneficial function by using hygroscopic materials within the sealing structure to actively capture and retain moisture molecules that penetrate the barrier layers. This transforms what would be a degradation mechanism into a protective mechanism that prevents moisture from reaching the electronic device components.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

Different layers in the sealing structure are assigned different functional properties: the inorganic layers provide moisture barrier properties while the organic layers with hygroscopic materials provide moisture adsorption capacity. This local differentiation of material properties allows each layer to perform its specific function optimally without compromising the overall sealing performance.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively prevents moisture ingress, enhances the sealing layer's hygroscopic properties, and improves the durability and performance of electronic devices by maintaining a stable moisture-adsorbing ability.

Implementation Method 1

utilizing the metal (meth)acrylate's ability to adsorb water molecules through hydrogen bonding or ion-dipole interactions

Methodology Applied
Scientific EffectHydrogen bonding:

Implementation Method 2

utilizing the metal (meth)acrylate's ability to adsorb water molecules through hydrogen bonding or ion-dipole interactions

Methodology Applied
Scientific EffectIon-dipole interaction:

Data Source

PatentUS10501655B2Organic film forming composition and electronic apparatus comprising a cured product thereof
Publication Date: 2019.12.10 SAMSUNG DISPLAY CO LTD
  • US10501655B2 patent drawing
  • US10501655B2 patent drawing
  • US10501655B2 patent drawing

AI summary

An organic film forming composition having improved hygroscopic properties (e.g., moisture-adsorbing abilities) and an electronic apparatus including a cured product of the organic film forming composition. The organic film forming composition may include a metal (meth)acrylate represented by Formula 1; and a curable material having at least two curable groups selected from the groups represented by Formulae 2A to 2D: