3D Printing Metal Nanoparticle Sintering Control

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Solution Overview

Problem

Current 3D printing techniques face challenges in achieving accurate and detailed features due to issues with fluid splashing and bubbling, which affect the formation of metal connections between build material particles, leading to reduced mechanical strength and dimensional accuracy of the printed parts.

Innovation Solution

A method involving the selective application of a fluid containing metal nanoparticles to a layer of metal build material particles, where the metal nanoparticles are sintered or melted without melting the build material particles, forming connections that bind the particles together, while controlling printing parameters such as temperature, fluid loading, and heating events to minimize undesirable effects like splashing and bubbling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If heat-assisted extrusion or sintering is used to bind metal particles together, then mechanical strength is improved, but fluid splashing and bubbling occur leading to reduced manufacturing precision

Engineering Contradiction:
Improvemechanical strengthVSAvoiddimensional accuracy
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by precisely controlling temperature, fluid loading, and heating event parameters to sinter metal nanoparticles without causing fluid splashing or bubbling. The controller adjusts these parameters to maintain the build material at a temperature sufficient for nanoparticle sintering while avoiding conditions that cause harmful fluid behavior, thereby achieving both mechanical strength and dimensional accuracy.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements periodic action through multiple heating events separated by delay periods. The controller applies heating events in sequence with controlled intervals, allowing the build material to reach optimal sintering temperature without excessive heat accumulation that would cause fluid bubbling. This periodic heating approach enables progressive binding of metal particles while maintaining manufacturing precision.

Inventive Principle:
Principle #19Periodic action

2Strength

If metal nanoparticles are sintered to form connections between particles, then mechanical strength is improved, but mass loss occurs during sintering

Engineering Contradiction:
Improvebreaking strengthVSAvoidmass loss
Core Design Contradiction:
StrengthVSLoss of substance

Solution Approach 1:

The patent minimizes mass loss during sintering by optimizing temperature and heating time parameters. The controller maintains the build material at a temperature that is sufficient to sinter metal nanoparticles and form strong connections, but controlled to prevent excessive evaporation or oxidation of the metal particles. This parameter optimization achieves breaking strength up to 20 MPa while minimizing mass loss.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If fluid loading is increased to ensure complete wetting of build material layer, then binding effectiveness is improved, but fluid splashing and bubbling increase

Engineering Contradiction:
Improvebinding effectivenessVSAvoidfluid splashing and bubbling
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent resolves this contradiction by precisely controlling fluid loading parameters and temperature conditions. The controller adjusts the amount of fluid applied and the temperature of the build material to achieve complete wetting of the metal particles without creating conditions that cause splashing or bubbling. This optimized parameter combination ensures reliable binding effectiveness while eliminating harmful fluid behavior.

Inventive Principle:
Principle #35Parameter changes

4Productivity

If heating temperature is increased to accelerate sintering process, then productivity is improved, but dimensional accuracy deteriorates

Engineering Contradiction:
Improvesintering speedVSAvoiddimensional accuracy
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent maintains dimensional accuracy during accelerated sintering by using periodic heating events with controlled delay periods. The controller applies heating in multiple controlled pulses rather than continuous high-temperature exposure, allowing the metal nanoparticles to sinter rapidly while preventing excessive heat that would cause fluid bubbling and dimensional distortion. This achieves both high productivity and dimensional accuracy.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of mechanically strong green parts with features down to 200 μm, maintaining dimensional accuracy and reducing mass loss during sintering, resulting in parts with breaking strength up to 20 MPa, which can be handled and further processed into dense 3D metal parts.

Implementation Method 1

exposing the metal nanoparticles to a sintering temperature that is higher than the print temperature and at least 500° below a melting point of the metal build material particles, thereby binding the metal build material particles together

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 2

at least partial melting may be accomplished using heat-assisted extrusion

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 3

exposing the metal nanoparticles to a sintering temperature that is higher than the print temperature and at least 500° below a melting point of the metal build material particles

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentUS11338363B2Three-dimensional printing
Publication Date: 2022.05.24 PERIDOT PRINT LLC
  • US11338363B2 patent drawing
  • US11338363B2 patent drawing
  • US11338363B2 patent drawing

AI summary

At a print temperature, a layer (having a predetermined height) of metal build material particles is formed. Also at the print temperature, a fluid containing metal nanoparticles is selectively applied to at least a portion of the layer, and at a fluid loading that wets the portion through the predetermined height without saturating the portion. The metal nanoparticles are exposed to a sintering temperature that is higher than the print temperature and at least 500° below a melting point of the metal build material particles using a predetermined number of heating events taking place at a predetermined speed or for a predetermined time, and separated by a predetermined delay time, to bind the metal build material particles together to form a bound layer. A build material surface is cooled to or below the print temperature. The forming, selectively applying, exposing, and cooling are repeated to form a part precursor.