Metal Nanowire Transparent Electrodes for OLED Light Extraction

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Solution Overview

Problem

Conventional OLEDs suffer from low light out-coupling efficiency due to total internal reflection at the interface between the organic stack and the substrate, leading to a significant portion of generated light being waveguided rather than externally emitted.

Innovation Solution

Incorporating a nanostructure layer with metal nanostructures and an anti-reflective layer between the substrate and the organic stack, which reduces waveguide modes and enhances light out-coupling by modifying the refractive index profile and introducing scattering centers to extract trapped light.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If a conventional OLED structure with transparent electrodes is used, then the device can emit light, but a substantial portion of the generated light is waveguided due to total internal reflection at the interface between the organic stack and substrate, resulting in low light out-coupling efficiency

Engineering Contradiction:
Improvelight out-coupling efficiencyVSAvoidoptical stack structure
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

An anti-reflective layer with intermediate refractive index (1.7-1.9) is introduced between the substrate (refractive index ~1.5) and the organic stack (refractive index ~1.7-1.8). This intermediary layer reduces the refractive index mismatch at the interface, minimizing total internal reflection and waveguide modes while maximizing light out-coupling efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The refractive index profile of the optical stack is modified by introducing the anti-reflective layer with a specific refractive index range (1.7-1.9). This parameter change optimizes the optical impedance matching between layers, reducing reflection losses and improving light extraction efficiency without requiring complex multi-layer structures.

Inventive Principle:
Principle #35Parameter changes

2Loss of energy

If the refractive index mismatch between the organic stack and substrate is reduced to minimize total internal reflection, then light out-coupling efficiency improves, but the device structure becomes more complex

Engineering Contradiction:
Improvewaveguided light energyVSAvoidnumber of layers
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

A single anti-reflective layer serves as an intermediary between the substrate and organic stack, providing optimal refractive index matching. This simple single-layer approach achieves effective light out-coupling enhancement without the complexity of multiple alternating high-index and low-index layers.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

By carefully selecting the refractive index of the anti-reflective layer (1.7-1.9) and optimizing its thickness, the patent achieves maximum light extraction efficiency with a minimal structural modification. The parameter optimization allows a single layer to perform the function that would otherwise require complex multi-layer interference structures.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Significantly improves light out-coupling efficiency by reducing waveguided light energy density and maximizing external light emission, thereby enhancing the performance of OLEDs and photovoltaic cells.

Implementation Method 1

modifying the refractive index profile

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 2

total internal reflection at the interface between the organic stack and the substrate

Methodology Applied
Scientific EffectTotal internal reflection: Total Internal Reflection

Implementation Method 3

introducing scattering centers to extract trapped light

Methodology Applied
Scientific EffectScattering: Scattering

Data Source

PatentUS10964890B2Opto-electrical devices incorporating metal nanowires
Publication Date: 2021.03.30 PINE CASTLE INVESTMENTS LTD
  • US10964890B2 patent drawing
  • US10964890B2 patent drawing
  • US10964890B2 patent drawing

AI summary

The present disclosure relates to OLED and PV devices including transparent electrodes that are formed of conductive nanostructures and methods of improving light out-coupling in OLED and input-coupling in PV devices.