Metal Oxide Electrode Uniformity for OLED Life Extension

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Solution Overview

Problem

Existing organic electroluminescence devices face challenges in achieving high efficiency and long life due to limitations in forming favorable thin films and maintaining stability under electric current, with previous methods focusing on increasing efficiency rather than addressing degradation mechanisms.

Innovation Solution

The development of an organic electroluminescence device with a metal oxide electrode having a uniform composite ratio of compounds from the surface through the bulk layer, ensuring stability and optimal conditions for extended life, involves using a metal oxide electrode made of elements like In, Sn, Zn, Fe, Co, Sr, Cu, Ag, Pt, or W, with specific properties such as high light transmittance, low sheet resistivity, and controlled surface roughness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If a metal oxide electrode with uniform composite ratio is used, then device stability and life are improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improvedevice lifeVSAvoidcomposite ratio uniformity
Core Design Contradiction:
Duration of action of stationary objectVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by controlling the composite ratio of metal oxides (such as In, Sn, Zn, Fe, Co, Sr, Cu, Ag, Pt, or W) in the electrode to achieve uniform distribution from surface through bulk layer. This uniform composition parameter directly improves device stability and extends operational life while maintaining manufacturability through standard deposition techniques.

Inventive Principle:
Principle #35Parameter changes

2Use of energy by moving object

If high light transmittance and low sheet resistivity are achieved, then out-coupling efficiency is improved, but material selection and deposition control complexity increase

Engineering Contradiction:
Improveout-coupling efficiencyVSAvoidelectrode structure
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent employs composite materials by combining multiple metal oxides (In, Sn, Zn, Fe, Co, Sr, Cu, Ag, Pt, or W) in specific ratios to create an electrode that simultaneously achieves high light transmittance and low sheet resistivity. This composite approach optimizes out-coupling efficiency without requiring complex multi-layer structures, as the uniform composite ratio itself provides the desired electrical and optical properties.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances out-coupling efficiency, reduces power consumption, and extends the life of the device by maintaining stability and optimal conditions, enabling more efficient light emission and longer operational life without altering the basic emission section structure.

Implementation Method 1

positive and negative carriers being injected through the electrode into and transported in the organic emission layer to cause the organic emission layer to generate light with recombination of a hole and an electron produced from the positive and negative carriers

Methodology Applied
Scientific EffectCarrier injection:

Implementation Method 2

positive and negative carriers being injected through the electrode into and transported in the organic emission layer to cause the organic emission layer to generate light with recombination of a hole and an electron produced from the positive and negative carriers

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 3

the fluorescent layer or phosphorescent layer receiving light from the organic emission layer to generate light secondarily

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 4

the fluorescent layer or phosphorescent layer receiving light from the organic emission layer to generate light secondarily

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentUS7612497B2Organic electroluminescence device and organic electroluminescence system
Publication Date: 2009.11.03 SAMSUNG DISPLAY CO LTD
  • US7612497B2 patent drawing
  • US7612497B2 patent drawing
  • US7612497B2 patent drawing

AI summary

An organic electroluminescence device is provided which employs a metal oxide electrode having particular composition distribution of elements to extend the life. A conventional approach for extending the life of an electroluminescence device is not provided by considering the degradation mechanism of how the organic electroluminescence device is degraded by the driving with electric current. The composite ratio of compounds of an electrode made of metal oxide forming part of the organic electroluminescence device is substantially uniform from a surface through which the carriers are injected from the electrode toward a deeper section in a bulk layer of the electrode. Thus, the electrode has stoichiometrically stable composition to prevent the degradation of electrode materials and diffusion into the organic layer, thereby providing a longer life.