Metal Oxide Semiconductor Channel Hydrogen Diffusion Control

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Solution Overview

Problem

Current semiconductor technologies face challenges in producing reliable semiconductor devices with stable electrical characteristics, low power consumption, and high integration capabilities due to issues with hydrogen diffusion and oxygen vacancies in oxide semiconductor channels.

Innovation Solution

A metal oxide with a c-axis aligned crystal structure, containing indium and elements like gallium, aluminum, or tin, is used in the channel formation region, with a hydrogen diffusion length of 200 nm or less and low absorption due to localized states, formed through a deposition and heat treatment process that inhibits hydrogen diffusion and reduces oxygen vacancies.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If oxide semiconductor is used in transistor channel, then low power consumption is achieved, but hydrogen diffusion causes instability in electrical characteristics

Engineering Contradiction:
Improvepower consumptionVSAvoidstability of electrical characteristics
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent changes the physical and chemical parameters of the oxide semiconductor by controlling oxygen vacancy concentration and hydrogen content through specific deposition conditions (oxygen partial pressure, substrate temperature) and post-deposition heat treatment, thereby reducing hydrogen diffusion and stabilizing electrical characteristics while maintaining low power consumption

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs inert or oxidizing atmosphere during deposition and heat treatment processes to prevent hydrogen incorporation and reduce oxygen vacancies, creating a stable oxide semiconductor channel that resists hydrogen diffusion and maintains reliable electrical characteristics

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Use of energy by moving object

If oxide semiconductor channel is used, then low power consumption is achieved, but variations in transistor characteristics increase

Engineering Contradiction:
Improvepower consumptionVSAvoiduniformity of transistor characteristics
Core Design Contradiction:
Use of energy by moving objectVSManufacturing precision

Solution Approach 1:

The patent optimizes deposition parameters (oxygen partial pressure ratio, substrate temperature) and heat treatment conditions to control oxygen vacancy concentration and hydrogen content, reducing variations in transistor characteristics such as threshold voltage and on-state current while preserving low power consumption properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent performs preliminary heat treatment immediately after deposition to stabilize the oxide semiconductor structure before subsequent processing steps, preventing variations in transistor characteristics by establishing a consistent baseline state early in the manufacturing process

Inventive Principle:
Principle #10Preliminary action

3Ease of manufacture

If conventional oxide semiconductor is used, then device fabrication is simplified, but on-state current is insufficient

Engineering Contradiction:
Improvefabrication simplicityVSAvoidon-state current
Core Design Contradiction:
Ease of manufactureVSPower

Solution Approach 1:

The patent adjusts oxygen partial pressure and substrate temperature during deposition, and controls heat treatment temperature and atmosphere, to optimize carrier concentration and mobility in the oxide semiconductor channel, achieving high on-state current while maintaining fabrication simplicity through a single deposition process

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in semiconductor devices with improved reliability, reduced variations in transistor characteristics, high on-state current, and low power consumption, enabling miniaturization and high integration while maintaining stable electrical performance.

Implementation Method 1

The diffusion length of hydrogen in the metal oxide is 200 nm or less

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

performing heat treatment at a temperature higher than or equal to 500° C. and lower than or equal to 600° C. after the metal oxide film is deposited

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 3

The metal oxide film is deposited by a sputtering method using an In-M-Zn oxide target

Methodology Applied
Scientific EffectSputtering: Sputtering

Data Source

PatentUS20220320339A1Metal oxide, formation method of metal oxide, semiconductor device, and manufacturing method of semiconductor device
Publication Date: 2022.10.06 SEMICON ENERGY LAB CO LTD
  • US20220320339A1 patent drawing
  • US20220320339A1 patent drawing
  • US20220320339A1 patent drawing

AI summary

A novel metal oxide is provided. The metal oxide includes a c-axis aligned crystal and contains indium, an element M (M is gallium, aluminum, yttrium, or tin), and zinc. In the metal oxide, the diffusion length of hydrogen is 200 nm or less and absorption due to localized states measured by a CPM is 0.01/cm or less. The diffusion length of hydrogen is calculated with the temperature being 400° C. and 1 hour.