Antimicrobial Metal Oxide Layer Sustained Silver Ion Release

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Solution Overview

Problem

Soluble silver salts used for preventing microbial infections do not provide a prolonged release of silver ions, leading to frequent reapplication needs, which can be burdensome, especially for implanted medical devices.

Innovation Solution

An anti-microbial article comprising an occlusive layer, an absorbent substrate, a metal oxide layer with less than 40 wt.% non-oxidized metal, and a metal layer, designed to provide a sustained release of silver ions through controlled metal oxide formation, enhancing antimicrobial activity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If soluble silver salts are used to prevent microbial infections, then anti-microbial activity is achieved, but the release of silver ions is not prolonged and frequent reapplication is required

Engineering Contradiction:
Improveanti-microbial activityVSAvoidrelease duration of silver ions
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The patent employs a composite layered structure consisting of a metal layer (containing silver) and a metal oxide layer (containing silver oxide). This composite material design allows the metal layer to provide initial silver ion release while the metal oxide layer provides sustained release over an extended period, thereby resolving the contradiction between achieving anti-microbial activity and prolonging the release duration.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical state of silver from purely metallic (in soluble salts) to a combination of metallic and oxidized forms (in the layered structure). By controlling the oxidation state and creating a gradient from metal to metal oxide, the system achieves both immediate and prolonged silver ion release, extending the duration of action while maintaining anti-microbial effectiveness.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If soluble silver salts are applied frequently to maintain anti-microbial effect, then continuous protection is achieved, but the process becomes burdensome and impractical

Engineering Contradiction:
Improvecontinuous anti-microbial protectionVSAvoidease of reapplication
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent applies preliminary action by pre-structuring the anti-microbial coating as a layered composite of metal and metal oxide before application. This pre-engineered structure is designed to automatically provide prolonged silver ion release without requiring frequent human intervention for reapplication, thus maintaining continuous protection while greatly improving ease of operation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The layered metal-metal oxide structure serves itself by providing sustained silver ion release from the metal oxide layer after the initial metal layer has released its ions. This self-sustaining mechanism eliminates the need for frequent reapplication by the user, making the system both continuously effective and easy to operate.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The article achieves a more than 4 log reduction in bacterial growth within 7 days and provides a prolonged release of antimicrobial agents, reducing the need for frequent reapplication and enhancing antimicrobial activity.

Implementation Method 1

a metal oxide layer overlaying the substrate, wherein the metal oxide layer comprises an antimicrobial metal oxide

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

an absorbent substrate selected from foam, fabric, nonwoven, hydrocolloid, hydrogel, and combinations thereof

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentEP3373984B1Anti-microbial articles and methods of using same
Publication Date: 2020.12.23 3M INNOVATIVE PROPERTIES CO
  • EP3373984B1 patent drawingFigure 1~2

AI summary

An article having anti-microbial effect is provided. The article includes an occlusive layer; a substrate overlaying the occlusive layer, wherein the substrate having two opposing major surfaces; a metal oxide layer overlaying the substrate, wherein the metal oxide layer comprises a metal oxide and wherein the metal oxide layer comprises less than 40 wt.% non-oxidized metal; and a metal layer overlaying the metal oxide layer.