Metal Oxide Sensor Temperature Profiling for Nicotine Selectivity

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Metal oxide sensors struggle to accurately determine the nicotine content in gas mixtures as they are sensitive to multiple components at fixed temperatures, making it difficult to infer individual gas components from electrical resistance measurements.

Innovation Solution

A method involving a metal oxide sensor exposed to a temperature profile with controlled transitions between different temperature levels, allowing for the measurement of nicotine content by analyzing electrical resistance changes, and potentially using additional sensors to account for other components like carbon monoxide and VOCs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If metal oxide sensors are operated at a fixed temperature to maintain stable measurement conditions, then measurement stability is improved, but selectivity deteriorates because the sensor responds to multiple gas components simultaneously

Engineering Contradiction:
Improvemeasurement stabilityVSAvoidselectivity
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The sensor operates with dynamic temperature changes instead of a fixed temperature. The temperature is varied over time to create different operational states, allowing the sensor to selectively respond to different gas components at different temperatures. This dynamic approach enables nicotine-specific detection while maintaining measurement stability through controlled temperature cycling.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The measurement temperature is changed as a parameter to differentiate between gas components. By operating at multiple temperatures and evaluating the resistance changes across these temperature points, the system can distinguish nicotine from other gases. The nicotine content is determined by comparing resistance measurements at different temperatures, where nicotine exhibits characteristic response patterns.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If multiple temperature measurements are taken to improve selectivity and differentiate gas components, then measurement accuracy is improved, but energy consumption increases due to repeated heating cycles

Engineering Contradiction:
ImproveselectivityVSAvoidenergy consumption
Core Design Contradiction:
Measurement precisionVSUse of energy by moving object

Solution Approach 1:

The sensor performs periodic temperature cycling with distinct phases: heating to a first temperature, holding, heating to a second temperature, and holding. This periodic action allows multiple measurements to be taken in a structured sequence, enabling selectivity improvement while managing energy consumption through controlled cycling rather than continuous heating at multiple temperatures.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The sensor performs preliminary heating to a first temperature before proceeding to the second temperature. This preliminary action prepares the sensor surface and establishes a baseline measurement state, allowing for more efficient subsequent measurements. The staged heating approach optimizes energy usage by preparing the system in advance rather than directly heating to all required temperatures simultaneously.

Inventive Principle:
Principle #10Preliminary action

3Measurement precision

If the sensor is heated to high temperatures to enhance sensitivity to certain gas components, then sensitivity is improved, but energy consumption and response time increase

Engineering Contradiction:
ImprovesensitivityVSAvoidenergy consumption
Core Design Contradiction:
Measurement precisionVSUse of energy by moving object

Solution Approach 1:

The sensor uses periodic heating cycles that include both high-temperature phases for enhanced sensitivity and lower-temperature phases for energy conservation. The temperature is raised to a second (higher) temperature for a defined period to achieve sensitive detection, then maintained or reduced for evaluation. This periodic high-temperature action provides the necessary sensitivity while limiting overall energy consumption through controlled duration and cycling.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables quick, energy-efficient, and accurate measurement of nicotine content in gas mixtures, improving selectivity and sensitivity, and allowing for differentiation between fresh and residual nicotine emissions.

Implementation Method 1

Gas components change the electrical resistance of a metal oxide layer by adsorption thereon or absorption therein

Methodology Applied
Scientific EffectElectrical resistance change: Electrical Resistance

Implementation Method 2

Gas components change the electrical resistance of a metal oxide layer by adsorption thereon

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

Gas components change the electrical resistance of a metal oxide layer by adsorption thereon or absorption therein

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 4

one or multiple heating element(s) being situated to heat the metal oxide layer to a predefined temperature

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Data Source

PatentUS11592413B2Method for determining a nicotine content in a gas mixture
Publication Date: 2023.02.28 ROBERT BOSCH GMBH
  • US11592413B2 patent drawing
  • US11592413B2 patent drawing

AI summary

A method for determining a nicotine content in a gas mixture. The method includes exposing a metal oxide-based sensor to the gas mixture, applying a temperature profile over time to the metal oxide so that the temperature of the metal oxide, proceeding from a predetermined first temperature level, is brought to a predetermined second temperature level under controlled first transition conditions, and the temperature is brought from the second temperature level to a third predetermined temperature level under controlled second transition conditions, ascertaining a transient specific electrical resistance of the metal oxide at at least one certain point in time during the application with the temperature profile, and determining the nicotine content based on the ascertained resistance. A processing unit and a computer program product for carrying out the method are also described.