Metal Oxide Protective Film for Oxide Semiconductor Stability

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Solution Overview

Problem

The electrical conductivity of oxide semiconductors can vary due to the entry of water or hydrogen and release of oxygen during the manufacturing process of semiconductor devices, leading to unstable electric characteristics.

Innovation Solution

A semiconductor device with a metal oxide film as a protective layer, formed using materials from the same group as the oxide semiconductor, is used to suppress the entry and diffusion of water or hydrogen and the release of oxygen, ensuring a stable interface and reliable performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional protective film is used over the oxide semiconductor film, then the device structure is simple, but water or hydrogen enters the oxide semiconductor film and oxygen is released, causing variation in electric characteristics

Engineering Contradiction:
Improveelectric characteristics stabilityVSAvoidprotective film structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The protective film is divided into multiple layers: a first protective film in direct contact with the oxide semiconductor film and a second protective film formed over the first protective film. This segmentation allows the first layer to provide barrier functionality while the second layer provides additional protection, resolving the contradiction between reliability and structural simplicity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first protective film acts as an intermediary barrier between the oxide semiconductor film and the external environment. It prevents water and hydrogen from reaching the oxide semiconductor film while allowing the device structure to remain relatively simple.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If the oxide semiconductor film is exposed during manufacturing, then the manufacturing process is simple, but electrical conductivity changes due to water or hydrogen entry and oxygen release

Engineering Contradiction:
Improveelectrical conductivity stabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The first protective film is formed over the oxide semiconductor film before subsequent manufacturing steps. This preliminary protective action prevents water and hydrogen from entering the oxide semiconductor film during manufacturing processes, maintaining electrical conductivity stability without significantly complicating the manufacturing sequence.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If no protective film is used, then the device structure is simplest, but the interface characteristics are unstable and electric characteristics vary

Engineering Contradiction:
Improveinterface characteristics stabilityVSAvoidfilm layer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The first protective film is specifically positioned in direct contact with the oxide semiconductor film where interface stability is critical. This localized quality enhancement provides the necessary interface stability without requiring complex structures throughout the entire device.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a semiconductor device with stable electric characteristics and high reliability by preventing water and hydrogen entry and oxygen release, resulting in improved semiconductor performance.

Implementation Method 1

The metal oxide film can suppress entry and diffusion of water or hydrogen into the oxide semiconductor film

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

release of oxygen from the oxide semiconductor film can be suppressed

Methodology Applied
Scientific EffectOxygen release suppression:

Data Source

PatentUS9252279B2Semiconductor device and manufacturing method thereof
Publication Date: 2016.02.02 SEMICON ENERGY LAB CO LTD
  • US9252279B2 patent drawing
  • US9252279B2 patent drawing
  • US9252279B2 patent drawing

AI summary

To provide a semiconductor device including an oxide semiconductor, which has stable electric characteristics and has high reliability. To provide a method for manufacturing the semiconductor device. The semiconductor device includes a gate electrode, a gate insulating film formed over the gate electrode, an oxide semiconductor film formed over the gate insulating film, a source electrode and a drain electrode formed over the oxide semiconductor film, and a protective film. The protective film includes a metal oxide film, and the metal oxide film has a film density of higher than or equal to 3.2 g/cm3.